{[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane

Base Information

Chemical Name:{[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane
CAS No.:104330-78-1
Molecular Formula:C11H17BrSi
Molecular Weight:257.245
Hs Code.:
DSSTox Substance ID:DTXSID10556821
Wikidata:Q82438519

Synonyms:104330-78-1;{[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane;DTXSID10556821

Suppliers and Price of {[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:256.02829
Heavy Atom Count:13
Complexity:151

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)(C)CC1=CC=CC=C1CBr

Technology Process of {[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane

There total 4 articles about {[2-(Bromomethyl)phenyl]methyl}(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 57754-01-5
2-[(trimethylsilyl)methyl]benzyl alcohol

: 104330-78-1
2-(trimethylsilylmethyl)benzyl bromide

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In diethyl ether; at 25 ℃; for 0.5h;
DOI:10.1021/ja00243a029

Reference yield:

: 89-95-2
2-methyl-benzyl alcohol

: 104330-78-1
2-(trimethylsilylmethyl)benzyl bromide

Guidance literature:: Multi-step reaction with 3 steps

1: 1) n-BuLi / 1) Et₂O, hexane, 0 deg C to room temperature; reflux, 24 h, 2) Et₂O, hexane, -78 deg C to room temperature; room temperature, 2 h

2: 112.6 g / 10percent H₂SO₄ / diethyl ether; hexane

3: 95 percent / PBr₃ / diethyl ether / 2 h / Ambient temperature

With n-butyllithium; sulfuric acid; phosphorus tribromide; In diethyl ether; hexane;
DOI:10.1021/jo970592c

Reference yield:

: 83781-92-4
o-[(trimethylsilyl)methyl]benzyl trimethylsilyl ether

: 104330-78-1
2-(trimethylsilylmethyl)benzyl bromide

Guidance literature:: Multi-step reaction with 2 steps

1: 112.6 g / 10percent H₂SO₄ / diethyl ether; hexane

2: 95 percent / PBr₃ / diethyl ether / 2 h / Ambient temperature

With sulfuric acid; phosphorus tribromide; In diethyl ether; hexane;
DOI:10.1021/jo970592c