Zn(((CH₃)3C)2C₆H₃C)4(C₄H₂N)3C₄N(NO₂)2

Base Information

• Chemical Name: Zn(((CH₃)3C)2C₆H₃C)4(C₄H₂N)3C₄N(NO₂)2
• CAS No.: 332110-41-5
• Molecular Formula: C₇₆H₉₀N₆O₄Zn
• Molecular Weight: 1216.98
• Mol file: 332110-41-5.mol

Synonyms:

Chemical Property of Zn(((CH₃)3C)2C₆H₃C)4(C₄H₂N)3C₄N(NO₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn(((CH₃)3C)2C₆H₃C)4(C₄H₂N)3C₄N(NO₂)2

There total 1 articles about Zn(((CH₃)3C)2C₆H₃C)4(C₄H₂N)3C₄N(NO₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

sodium tetrahydroborate (16940-66-2) + [2,3-diamino-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (185447-30-7) → Zn(((CH3)3C)2C6H3C)4(C4H2N)3C4N(NO2)2 (332110-41-5)

Guidance literature:

With 10percent palladium on activated carbon; In methanol; dichloromethane; addn. of 10% Pd-C to a soln. of copper complex in CH2Cl2-methanol mixt. (4:1), degassing with N2, addn. of NaBH4, stirring at room temp. in the dark under N2 for 1 h; evapn., passing through a plug of silica (CH2Cl2), evapn.;

DOI:10.1039/b007389j

Reference yield: 78.0%

Zn(((CH3)3C)2C6H3C)4(C4H2N)3C4N(NO2)2 (332110-41-5) → [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II) (214962-08-0)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; addn. of Dess-Martin periodinane to a soln. of zinc complex in CH2Cl2, stirring at room temp. in the dark for 25 min; passing through a plug of silica (CH2Cl2), evapn., column chromy (SiO2, CH2Cl2/light petroleum 2:3);

DOI:10.1039/b007389j

upstream raw materials:

sodium tetrahydroborate

[2,3-diamino-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Downstream raw materials:

[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)