[dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate

Base Information

• Chemical Name: [dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate
• CAS No.: 175876-10-5
• Molecular Formula: C₂₄H₂₀B*C₃₁H₅₉O₄P₂Ru
• Molecular Weight: 978.058
• Mol file: 175876-10-5.mol

Synonyms:

Chemical Property of [dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate

There total 1 articles about [dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) (175876-08-1) + sodium tetraphenyl borate (143-66-8) → [dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate (175876-10-5)

Guidance literature:

In dichloromethane; byproducts: NaCl; Ar-atmosphere; equimolar amts., stirring at room temp. for 24 h; solvent removal (reduced pressure), dissoln. in CH2Cl2, filtration off of NaCl, evapn. (vac.), washing (pentane), collection (filtration), drying (reduced pressure); elem. anal.;

DOI:10.1016/0022-328X(95)05817-9

Reference yield: 100.0%

[dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate (175876-10-5) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → [dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(η(1)-sulphur dioxide)(triethyl phosphite)ruthenium(II)tetraphenylborate (175923-82-7)

Guidance literature:

In dichloromethane; absence of air and moisture; bubbling SO2 for 5 min, stirring for 5 min; solvent removal (reduced pressure), washing (pentane), collection (filtration), drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(95)05817-9

upstream raw materials:

chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II)

sodium tetraphenyl borate

Downstream raw materials:

[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(η(1)-sulphur dioxide)(triethyl phosphite)ruthenium(II)tetraphenylborate