chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II)

Base Information

• Chemical Name: chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II)
• CAS No.: 175876-08-1
• Molecular Formula: C₃₁H₅₉ClO₄P₂Ru
• Molecular Weight: 694.278
• Mol file: 175876-08-1.mol

Synonyms:

Chemical Property of chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II)

There total 1 articles about chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)ruthenium(II) (165193-78-2) + triethyl phosphite (122-52-1) → [RuCl(η5-C5Me5){P(OEt)3}2] + chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) (175876-08-1)

Guidance literature:

In toluene; Ar-atmosphere; equimolar amts., stirring at room temp. for 15 min; evapn., dissoln. in hexane, chromy. (SiO2, hexane; then hexane/Et2O=2:1), solvent removal, drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(95)05817-9

Reference yield: 82.0%

chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) (175876-08-1) + sodium tetraphenyl borate (143-66-8) → [dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate (175876-10-5)

Guidance literature:

In dichloromethane; byproducts: NaCl; Ar-atmosphere; equimolar amts., stirring at room temp. for 24 h; solvent removal (reduced pressure), dissoln. in CH2Cl2, filtration off of NaCl, evapn. (vac.), washing (pentane), collection (filtration), drying (reduced pressure); elem. anal.;

DOI:10.1016/0022-328X(95)05817-9

upstream raw materials:

chloro[dicyclohexyl(2-methoxyethyl)phosphine-P](pentamethylcyclopentadienyl)ruthenium(II)

triethyl phosphite

Downstream raw materials:

[dicyclohexyl(2-methoxyethyl)phosphine-O,P](pentamethylcyclopentadienyl)(triethyl phosphite)ruthenium(II) tetraphenylborate