{(P(C₆H₅)3)2RuB₁₀H₈(OC₂H₅)2}

Base Information

• Chemical Name: {(P(C₆H₅)3)2RuB₁₀H₈(OC₂H₅)2}
• CAS No.: 93402-49-4
• Molecular Formula: C₄₀H₄₈B₁₀O₂P₂Ru
• Molecular Weight: 831.947
• Mol file: 93402-49-4.mol

Synonyms:

Chemical Property of {(P(C₆H₅)3)2RuB₁₀H₈(OC₂H₅)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(P(C₆H₅)3)2RuB₁₀H₈(OC₂H₅)2}

There total 2 articles about {(P(C₆H₅)3)2RuB₁₀H₈(OC₂H₅)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + bis(triethylammonium)-decahydro-closo-decaborate → 3P(C6H5)3*2Cl(1-)*Ru2(B10H8)(4+)*2C2H5O(1-)=[(P(C6H5)3)2ClRuClRu(P(C6H5)3)B10H8(OC2H5)2] + {(P(C6H5)3)2RuB10H8(OC2H5)2} (93402-49-4)

Guidance literature:

With ethanol; In ethanol; byproducts: H2, P(C6H5)3, Cl(1-); (NEt3H)2(B10H10) and (RuCl2(PPh3)3) dissolved in EtOH and heated under reflux for 3 h under N2; soln. reduced in volume and chromed using CH2Cl2-light petroleum (4:1) as eluant; Ru complex recrystd. from CH2Cl2/n-pentane; probably formation of traces of dinuclear Ru complex; elem. anal.;

Reference yield: 40.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + [B10H10](2-) → {(P(C6H5)3)2RuB10H8(OC2H5)2} (93402-49-4)

Guidance literature:

With ethanol; In ethanol; chloroform;

DOI:10.1016/S0277-5387(00)84643-4

Reference yield: 19.0%

{(P(C6H5)3)2RuB10H8(OC2H5)2} (93402-49-4) + trimethylphosphane (594-09-2) → {(P(C6H5)3)(P(CH3)3)RuB10H8(OC2H5)2} (113903-56-3)

Guidance literature:

In dichloromethane; under vac., PMe3 (prepd. by dissociation of (AgI(PMe3))4) condensed into a stirred soln. of the complex at -78°C, allowed to warm to room temp., stirred for 1 h; concd., thin layer chromy. (CH2Cl2/n-hexane);

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

Downstream raw materials:

{(P(C₆H₅)3)(P(CH₃)3)RuB₁₀H₈(OC₂H₅)2}