[tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II)

Base Information

• Chemical Name: [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II)
• CAS No.: 42401-87-6
• Molecular Formula: C₈N₄PtS₄*2C₁₆H₃₆N
• Molecular Weight: 960.396
• Mol file: 42401-87-6.mol

Synonyms:

Chemical Property of [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II)

There total 1 articles about [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

potassium tetrachloroplatinate(II) (10025-99-7) + tetrabutyl-ammonium chloride (1112-67-0) + disodium maleonitriledithiolato → [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II) (42401-87-6)

Guidance literature:

In ethanol; water; aq. soln. of K2PtCl4 added to soln. of Na2(NCCS)2 (H2O/EtOH); filtered; Bu4NCl in EtOH added to filtrate; ppt. filtered; washed (H2O/EtOH); dried (air); dissolved (acetone) at 60°C; filtered; filtrate heated to boiling temp.; acetone partial evapd.; cooled to roon temp.; isobutanol added; allowed to stand at room temp.; ppt. filtered; washed; dried;

DOI:10.1016/S0020-1693(01)00551-5

Reference yield: 42.0%

Au(triphenylphosphine)(NO3) (14897-32-6) + [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II) (42401-87-6) → bis(maleonitrildithiolato)platinumbis(triphenylphosphinegold(I))

Guidance literature:

In methanol; to a suspn. of excess Ph3PAuNO3 in MeOH the Pt-complex is added with stirring, mixt. is stirred for 3 h at room temp.; ppt. is centrifugated, washed with MeOH three times and dried in high vac., diffusion of diethyl ether into the soln. leads to crystn., elem. anal.;

Reference yield: 38.0%

pentacarbonyl(tetrafluoroborato)rhenium (78670-75-4) + [tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)platinate(II) (42401-87-6) → tetrabutylammonium bis(maleonitriledithiolato)platinum (pentacarbonylrhenium(I))

Guidance literature:

In methanol; dichloromethane; to a soln. of Pt-complex in CH2Cl2 a soln. of (CO)5ReBF4 in MeOH is added with stirring, mixt. is stirred for 1 h at room temp.; solvent is evapd., dissolving in isopropanol; stirring overnight, ppt. is centrifugated; washed three times in isopropanol/water and dried in high vac., further purification by chromy. (silica gel, CH2Cl2/isopropanol (4:1); second fraction; elem. anal.;;

upstream raw materials:

potassium tetrachloroplatinate(II)

tetrabutyl-ammonium chloride

Downstream raw materials:

[1,1'-dibenzyl-4,4'-bipyridinium][Pt(maleonitriledithiolate)2]