(1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate

Base Information

• Chemical Name: (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate
• CAS No.: 116076-50-7
• Molecular Formula: C₁₀H₂₀O₆S₂
• Molecular Weight: 300.397
• Mol file: 116076-50-7.mol

Synonyms:

Chemical Property of (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate

There total 3 articles about (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-dimethyl 1,4-cyclohexanedicarboxylate (3399-21-1) → (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate (116076-50-7,35541-77-6)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄; diethyl ether

2: pyridine

With pyridine; lithium aluminium tetrahydride; diethyl ether;

DOI:10.1039/jr9530000399

Reference yield:

(1s,4s)-cyclohexane-1,4-diyldimethanol (3236-47-3) + methanesulfonyl chloride (124-63-0) → (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate (116076-50-7,35541-77-6)

Guidance literature:

With pyridine;

DOI:10.1039/jr9530000399

Reference yield:

→ (1,4-cis-cyclohexanediyl)bis(methylene)dimethanesultonate (116076-50-7,35541-77-6)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 7h;

upstream raw materials:

(1s,4s)-cyclohexane-1,4-diyldimethanol

methanesulfonyl chloride

cis-dimethyl 1,4-cyclohexanedicarboxylate

Downstream raw materials:

4-methylene-1-cyclohexanemethanol

(1s,4s)-cyclohexane-1,4-diyldimethanol

cis-1,4-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane

cis-1,4-bis-(acetylsulfanyl-methyl)-cyclohexane