[RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl

Base Information

• Chemical Name: [RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl
• CAS No.: 1228235-79-7
• Molecular Formula: C₂₄H₂₆ClN₄Ru*Cl
• Molecular Weight: 542.473
• Mol file: 1228235-79-7.mol

Synonyms:

Chemical Property of [RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl

There total 1 articles about [RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2-{[4-phenyl-1H-1,2,3-triazol-1-yl]methyl}pyridine (1192206-01-1) → [RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl (1228235-79-7)

Guidance literature:

In ethanol; mixt. ligand and Ru complex in EtOH was stirred at room temp. for 2 days; hexane was added and left to stand at 4°C for 2 h, soln. was filtered and evapd.;

DOI:10.1021/ic902354e

Reference yield: 82.0%

[RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl (1228235-79-7) + silver nitrate → [Ag2(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)2(NO3)2] (1228235-77-5)

Guidance literature:

In methanol; soln. AgNO3 in MeOH was added dropwise to soln. ligand in MeOH, stirred for 24 h; ppt. was filtered and washed with MeOH and Et2O; elem. anal.;

DOI:10.1021/ic902354e

Reference yield:

[RuCl(η6-p-cymene)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)]Cl (1228235-79-7) + water-d2 (7789-20-0) → [Ru(η6-p-cymene)(D2O)(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)](2+)

Guidance literature:

In water-d2; dissolving Ru complex in D2O; NMR detection;

DOI:10.1039/c0dt01807d

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

2-{[4-phenyl-1H-1,2,3-triazol-1-yl]methyl}pyridine

Downstream raw materials:

[Ag₂(1-(2-picolyl)-4-phenyl-1H-1,2,3-triazole)2(NO₃)2]