(PtCl₂(CO)P(C₆H₄F)3)

Base Information

• Chemical Name: (PtCl₂(CO)P(C₆H₄F)3)
• CAS No.: 76705-01-6
• Molecular Formula: C₁₉H₁₂Cl₂F₃OPPt
• Molecular Weight: 610.259
• Mol file: 76705-01-6.mol

Synonyms:

Chemical Property of (PtCl₂(CO)P(C₆H₄F)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (PtCl₂(CO)P(C₆H₄F)3)

There total 1 articles about (PtCl₂(CO)P(C₆H₄F)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + P(p-C6H4F)3 (18437-78-0) → (PtCl2(CO)P(C6H4F)3) (76705-01-6)

Guidance literature:

With carbon monoxide; In chloroform; CO passed through suspn. (PtCl2(cod)) in chloroform, after 1 h, chloroform soln. P(C6H4F-p)3 added dropwise over 30 min and CO passage continued over 30 min; soln. concd., ether added; elem. anal.;

DOI:10.1021/ic50220a003

Reference yield:

tin(II) chloride dihdyrate (10025-69-1) + (PtCl2(CO)P(C6H4F)3) (76705-01-6) → trans-[PtCl(CO)(P(p-FC6H4)3)2](1+) (83721-22-6)

Guidance literature:

In [⁽²⁾H₆]acetone; acetone; Pt complex mixed with 2.0 equiv of SnCl2*2H2O, solvents added, shook at25°C until clear soln. formed; not isolated, monitored by NMR;

Reference yield:

tin(II) chloride dihdyrate (10025-69-1) + cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1) + (PtCl2(CO)P(C6H4F)3) (76705-01-6) → trans-(triphenylphosphine)2Pt(CO)Cl(1+) (20683-70-9,32424-72-9,74924-19-9) + trans-[PtCl(CO)(P(C6H5)3)(P(p-FC6H4)3)](1+) (83731-23-1) + trans-[PtCl(CO)(P(p-FC6H4)3)2](1+) (83721-22-6)

Guidance literature:

In [⁽²⁾H₆]acetone; acetone; 2.0 equiv of SnCl2*2H2O added to equimolar mixt. of Pt complexes, solvents added, shook at 25°C until clear soln. formed; not isolated, monitored by NMR;

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

P(p-C₆H₄F)3

Downstream raw materials:

trans-[PtCl(CO)(P(p-FC₆H₄)3)2]⁽¹⁺⁾

trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾

trans-[PtCl(CO)(P(C₆H₅)3)(P(p-FC₆H₄)3)]⁽¹⁺⁾