(η5-C5H4CMe2Ph)TiCl3

Base Information

Chemical Name:(η5-C5H4CMe2Ph)TiCl3
CAS No.:345890-79-1
Molecular Formula:C₁₄H₁₅Cl₃Ti
Molecular Weight:337.512
Hs Code.:

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Chemical Property of (η5-C5H4CMe2Ph)TiCl3

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Technology Process of (η5-C5H4CMe2Ph)TiCl3

There total 1 articles about (η5-C5H4CMe2Ph)TiCl3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.8%

: 7550-45-0
titanium tetrachloride

: 345890-79-1,257615-18-2
(η5-C5H4CMe2Ph)TiCl3

Guidance literature:: With C₅H₄(SiMe₃)C(CH₃)2C₆H₅; In dichloromethane; N2-atmosphere; equimolar amts., stirring overnight; solvent removal, solidification on standing for 1 d, recrystn. (CH2Cl2, -16°C); second batch from mother liquor; elem. anal.;
DOI:10.1016/S0022-328X(99)00488-X

Reference yield: 72.0%

: 345890-79-1,257615-18-2
(η5-C5H4CMe2Ph)TiCl3

: 1589-82-8
phenylmagnesium bromide

: 450410-96-5
[(η5-C5H4CMe2Ph)Ti(CH2Ph)3]

Guidance literature:: In diethyl ether; (N2); using Schlenk techniques; addn. dropwise of soln. of PhCH2MgBr (3 equiv.) in Et2O to stirred soln. of (C5H4CMe2Ph)TiCl3 in Et2O at -40°C; warming to room temp.; stirring for 3 h; removal of solvent in vac., extn. with pentane, cooling to -40°C;crystn.; elem. anal.;
DOI:10.1021/om0206554

Reference yield: 62.0%

: 345890-79-1,257615-18-2
(η5-C5H4CMe2Ph)TiCl3

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 481695-47-0
[(η5-C5H4CMe2Ph)Ti(CH2SiMe3)3]

Guidance literature:: In diethyl ether; (N2); using Schlenk techniques; addn. dropwise of soln. ClMgCH2SiMe3 (3 equiv.) in diethyl ether to soln. of (C5H4CMe2Ph)TiCl3 in Et2O cooled to-70°C; warming to room temp.; stirring for 3 h; removal of volatiles in vac., extn. with pentane, pumping of pentane; asoil;
DOI:10.1021/om0206554