bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine

Base Information

Chemical Name:bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine
CAS No.:223411-76-5
Molecular Formula:C₄₂H₄₆Cl₂N₂O₂Si₂Zr
Molecular Weight:829.14
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine

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Technology Process of bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine

There total 2 articles about bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: bis(triphenylsiloxo)-zirconium(IV)-chloride-bis-tetrahydrofurane-bis-toluene

: 223411-76-5
bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine

Guidance literature:: In tetrahydrofuran; Ar-atmosphere; addn. of slight excess of diamine to Zr-complex (25°C, stirring); solvent removal, drying (vac.); elem. anal.;
DOI:10.1016/S0020-1693(98)00371-5

Reference yield:

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 10026-11-6
zirconium(IV) chloride

: 791-31-1
triphenylhydroxysilane

: 223411-76-5
bis(triphenylsiloxo)-zirconium(IV)-chloride-tetramethylethylenediamine

Guidance literature:: With BuLi; In hexane; toluene; byproducts: LiCl; Ar-atmosphere; addn. of BuLi (in hexane) to silanol (in PhMe) at -40°C, warming to 25°C, slow addn. to ZrCl4 suspn. (in PhMe), stirring for 1 h, filtration off of LiCl, addn. of diamine; evapn., drying (vac.);
DOI:10.1016/S0020-1693(98)00371-5