3-(1-adamantyl)-1-[(2-diphenylphosphinoferrocenyl)ethyl]-3H-imidazolium iodide

Base Information

• Chemical Name: 3-(1-adamantyl)-1-[(2-diphenylphosphinoferrocenyl)ethyl]-3H-imidazolium iodide
• CAS No.: 1016260-28-8
• Molecular Formula: C₃₇H₄₀FeN₂P*I
• Molecular Weight: 726.463
• Mol file: 1016260-28-8.mol

Synonyms:

Chemical Property of 3-(1-adamantyl)-1-[(2-diphenylphosphinoferrocenyl)ethyl]-3H-imidazolium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-(1-adamantyl)-1-[(2-diphenylphosphinoferrocenyl)ethyl]-3H-imidazolium iodide

There total 1 articles about 3-(1-adamantyl)-1-[(2-diphenylphosphinoferrocenyl)ethyl]-3H-imidazolium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(ScRp)-PPFOAc (74311-58-3,83378-24-9,74286-35-4) + 1-(1-adamantyl)-1H-imidazole (69380-11-6) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → 3-(1-adamantyl)-1-[(2-diphenylphosphinoferrocenyl)ethyl]-3H-imidazolium iodide (1016260-28-8)

Guidance literature:

In water; acetonitrile; under N2; MeCN and H2O added to racemic Fe complex and substituted imidazole; stirred at 25°C for 3 d; benzene added; org. phase sepd.; concd.; residue together with NaI dissolved in EtOH; stirred at 25°C for 4 h; solvent evapd.; column chromd. (silica gel, hexane-ethyl acetate 5:1, CH2Cl2-MeOH 95:5);

DOI:10.1039/b714892e

upstream raw materials:

(ScRp)-PPFOAc

1-(1-adamantyl)-1H-imidazole

sodium iodide