di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru)

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Chemical Name:di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru)
CAS No.:94658-87-4
Molecular Formula:C₃₆H₂₀O₈Ru₃
Molecular Weight:883.76
Hs Code.:

di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru)

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Chemical Property of di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru)

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Technology Process of di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru)

There total 4 articles about di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: (carbonyl)10(CH₃CN)2triruthenium

: 501-65-5
diphenyl acetylene

: (ruthenium)3(carbonyl)8(C₂(C₆H₅)2)2

: 94658-87-4,149477-08-7
di-μ-carbonyl-1:2κ(2)C;1:3κ(2)C-hexacarbonyl-1κ(2)C,2κ(2)C,3κ(2)C-μ(3)-[1,2,3,4-tetraphenyl-2(.eta(4)):3(η(4))-1,3-butadiene-1,4-diyl-1κ(2)C]-triruthenium(2 Ru-Ru)

Guidance literature:: In tetrahydrofuran; (C6H5C)2 (soln.) addn. to Ru-complex, refluxing for 4 h under N2-atmosphere; solvent removal (vac.), chromy. (TLC; SiO2, n-hexane);
DOI:10.1107/S0108270195002861

Reference yield: 40.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 501-65-5
diphenyl acetylene

: 94658-87-4
Ru₃(CO)8(PhC₂Ph)2

Guidance literature:: In toluene; refluxing, excess PhC2Ph;

Reference yield: 24.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 15308-61-9
(diphenylacetylene)bis(triphenylphosphine)platinum⁽⁰⁾

: RuPt₂(CO)5(PPh₃)2(PhC₂Ph)

: Ru₂Pt(CO)7(PPh₃)2(PhC₂Ph)

: Ru₃(CO)10(PPh₃)2

: 94658-87-4
di-μ-carbonylhexacarbonyl{μ3-{(1,2,3,4-η:1,2,3,4-η:1,4-η)-1,2,3,4-tetraphenyl-1,3-butadiene-1,4-diyl}}triruthenium (2Ru-Ru)

Guidance literature:: In toluene; under N2 atm. Ru3(CO)12 and Pt(PPh3)2(PhCCPh) were dissolved in toluene at 25°C, react. mixt. was heated to reflux for 30 min; react. mixt. was cooled, solvent was removed in vacuo, sepn. by TLC (hexane-dichloromethane 3:1) - other products - Ru4(CO)12(PhCCPh), Ru3(CO)11(PPh3), and Ru3(CO)7(PPh2)(μ-C6H5); elem. anal.;
DOI:10.1016/S0022-328X(00)00302-8