(C₄H₉)3PNP(C₆H₅)2NTi(CH₃)2C₅H₅

Base Information

• Chemical Name: (C₄H₉)3PNP(C₆H₅)2NTi(CH₃)2C₅H₅
• CAS No.: 348120-11-6
• Molecular Formula: C₃₁H₄₈N₂P₂Ti
• Molecular Weight: 558.563
• Mol file: 348120-11-6.mol

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Chemical Property of (C₄H₉)3PNP(C₆H₅)2NTi(CH₃)2C₅H₅

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of (C₄H₉)3PNP(C₆H₅)2NTi(CH₃)2C₅H₅

There total 1 articles about (C₄H₉)3PNP(C₆H₅)2NTi(CH₃)2C₅H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(C4H9)3PNP(C6H5)2NTiCl2C5H5 (348120-09-2) + methylmagnesium bromide (75-16-1) → (C4H9)3PNP(C6H5)2NTi(CH3)2C5H5 (348120-11-6)

Guidance literature:

In toluene; to a toluene soln. of C5H5TiCl3 was added (CH3)MgBr, the mixt. was stirred at room temp. overnight (N2); evapd., the solid was extd. with benzene-hexane, filtered, the solvent was removed in vac.; elem. anal.;

DOI:10.1021/om0101184

Reference yield: 10.0%

(C4H9)3PNP(C6H5)2NTi(CH3)2C5H5 (348120-11-6) + tris(pentafluorophenyl)borate (1109-15-5) → ((C4H9)3PNP(C6H5)2NTiC5H5Cl)2(2+)*2B(C6F5)4(1-)=((C4H9)3PNP(C6H5)2NTiC5H5Cl)2(B(C6F5)4)2

Guidance literature:

In dichloromethane; a CH2Cl2 soln. of B(C6F5)3 was added dropwise to a soln. of complex in CH2Cl2, the mixt. was stirred at room temp. for 2 weeks (N2); elem. anal.;

DOI:10.1021/om0101184

upstream raw materials:

(C₄H₉)3PNP(C₆H₅)2NTiCl₂C₅H₅

methylmagnesium bromide