(-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate

Base Information

Chemical Name:(-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate
CAS No.:77632-80-5
Molecular Formula:C₃₃H₄₄F₃NO₇
Molecular Weight:623.71
Hs Code.:

(-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4-<N-(3-methyl-2-butenyl)trifluoroacetamido>-2-butenoate

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Chemical Property of (-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate

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Technology Process of (-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate

There total 8 articles about (-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 92180-19-3,92180-21-7
(+)-phenylmenthyl(E)-4,4-diethoxycarbonyl-4-trifluoroacetamido-2-butenoate

: 870-63-3
prenyl bromide

: 77632-80-5,77648-70-5
(-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate

Guidance literature:: With sodium hydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; for 20h; Ambient temperature;
DOI:10.1016/S0040-4020(01)82424-8

Reference yield: 24.0%

: 92180-19-3,92180-21-7
(+)-phenylmenthyl(Z)-4,4-diethoxycarbonyl-4-trifluoroacetamido-2-butenoate

: 870-63-3
prenyl bromide

: 77632-80-5,77648-70-5
(+)-8-phenylmenthyl(Z)-4,4-diethoxycarbonyl-4--2-butenoate

Guidance literature:: With sodium hydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; for 20h; Ambient temperature;
DOI:10.1016/S0040-4020(01)82424-8

Reference yield:

: 65253-04-5
(-)-8-phenylmenthol

: 77632-80-5,77648-70-5
(-)-8-phenylmenthyl(E)-4,4-diethoxycarbonyl-4--2-butenoate

Guidance literature:: Multi-step reaction with 3 steps

1: dicyclohexylcarbodiimide, 4-dimethylaminopyridine

2: t-BuOK / 2-methyl-propan-2-ol

3: NaH / hexamethylphosphoric acid triamide

With dmap; potassium tert-butylate; sodium hydride; dicyclohexyl-carbodiimide; In N,N,N,N,N,N-hexamethylphosphoric triamide; tert-butyl alcohol;
DOI:10.1002/hlca.19800630729