[PhB(μ-Nt-Bu)2]AsN(t-Bu)H

Base Information

• Chemical Name: [PhB(μ-Nt-Bu)2]AsN(t-Bu)H
• CAS No.: 1152314-35-6
• Molecular Formula: C₁₈H₃₃AsBN₃
• Molecular Weight: 377.213
• Mol file: 1152314-35-6.mol

Synonyms:

Chemical Property of [PhB(μ-Nt-Bu)2]AsN(t-Bu)H

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PhB(μ-Nt-Bu)2]AsN(t-Bu)H

There total 1 articles about [PhB(μ-Nt-Bu)2]AsN(t-Bu)H which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[PhB(μ-Nt-Bu)2]AsCl (934734-81-3) + lithium tert-butylamide (37828-54-9) → [PhB(μ-Nt-Bu)2]AsN(t-Bu)H (1152314-35-6)

Guidance literature:

In diethyl ether; byproducts: LiCl; cold diethyl ether (-80°C) added to mixt. of Li-compd. and boraamidinate at -80°C, mixt. stirred at -80°C for 0.5 h and at room temp. for ca. 5 h; LiCl removed by filtration, filtrate evapd. under vac.; elem. anal.;

DOI:10.1002/zaac.200700543

Reference yield: 73.0%

n-butyllithium (109-72-8,29786-93-4) + [PhB(μ-Nt-Bu)2]AsN(t-Bu)H (1152314-35-6) → [PhB(μ-Nt-Bu)2]AsN(t-Bu)Li

Guidance literature:

In hexane; byproducts: butane; n-BuLi/hexane added to soln. of boroamidinateamide in hexane at -80°C, mixt. stirred at -80°C for 0.5 h and at room temp. for 15 h; soln. evapd., solid washed with cold n-hexane; elem. anal.;

DOI:10.1002/zaac.200700543

Reference yield:

[PhB(μ-Nt-Bu)2]AsN(t-Bu)H (1152314-35-6) → ([PhB(μ-Nt-Bu)2]AsN(t-Bu)H(LiI))2 (1152314-37-8)

Guidance literature:

Multi-step reaction with 2 steps

1: hexane

2: diethyl ether

In diethyl ether; hexane;

DOI:10.1002/zaac.200700543

upstream raw materials:

[PhB(μ-Nt-Bu)2]AsCl

lithium tert-butylamide

Downstream raw materials:

([PhB(μ-Nt-Bu)2]AsN(t-Bu)H(LiI))2