[PhB(μ-Nt-Bu)2]AsCl

Base Information

• Chemical Name: [PhB(μ-Nt-Bu)2]AsCl
• CAS No.: 934734-81-3
• Molecular Formula: C₁₄H₂₃AsBClN₂
• Molecular Weight: 340.536
• Mol file: 934734-81-3.mol

Synonyms:

Chemical Property of [PhB(μ-Nt-Bu)2]AsCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PhB(μ-Nt-Bu)2]AsCl

There total 2 articles about [PhB(μ-Nt-Bu)2]AsCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

arsenic trichloride (7784-34-1) + bis(tert-butylamino)phenylborane dilithium salt (124652-56-8) → [PhB(μ-Nt-Bu)2]AsCl (934734-81-3)

Guidance literature:

In diethyl ether; byproducts: LiCl; (Ar); a soln. of Li compd. added to a soln. of AsCl3 at -80°C, stirred for 0.5 h at -80°C and for ca 4 h at room temp.; filtered, evapd. (vac.); elem. anal.;

DOI:10.1021/ic0622757

Reference yield:

arsenic trichloride (7784-34-1) + bis(tert-butylamino)phenylborane dilithium salt (124652-56-8) → [PhB(μ-Nt-Bu)2]AsCl (934734-81-3) + LiAs[PhB(N(t)Bu)2]2

Guidance literature:

In diethyl ether; (Ar); obtained as a mixt.;

DOI:10.1021/ic0622757

Reference yield: 78.0%

[PhB(μ-Nt-Bu)2]AsCl (934734-81-3) + lithium tert-butylamide (37828-54-9) → [PhB(μ-Nt-Bu)2]AsN(t-Bu)H (1152314-35-6)

Guidance literature:

In diethyl ether; byproducts: LiCl; cold diethyl ether (-80°C) added to mixt. of Li-compd. and boraamidinate at -80°C, mixt. stirred at -80°C for 0.5 h and at room temp. for ca. 5 h; LiCl removed by filtration, filtrate evapd. under vac.; elem. anal.;

DOI:10.1002/zaac.200700543

upstream raw materials:

arsenic trichloride

bis(tert-butylamino)phenylborane dilithium salt

Downstream raw materials:

[PhB(μ-Nt-Bu)2]AsN(t-Bu)H

([PhB(μ-Nt-Bu)2]AsN(t-Bu)H(LiI))2