4-bromophenyl[3]ferrocenophane

Base Information

Chemical Name:4-bromophenyl[3]ferrocenophane
CAS No.:1309378-27-5
Molecular Formula:C₁₉H₁₇BrFe
Molecular Weight:381.095
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-bromophenyl[3]ferrocenophane

Chemical Property:

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Technology Process of 4-bromophenyl[3]ferrocenophane

There total 1 articles about 4-bromophenyl[3]ferrocenophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: [3]ferrocenophane

: 106-40-1
4-bromo-aniline

: 1309378-27-5
4-bromophenyl[3]ferrocenophane

Guidance literature:: With H₂SO₄; NaNO₂; NaOH; In diethyl ether; water; NaNO2 soln. added to mixt. of BrC6H4NH2, concd. H2SO4 and H2O at -5°C, soln. added to Fe(C5H4)2(CH2)3 soln. (in Et2O and CH3(CH2)15(CH3)3NBr) at 0°C, stirred for 3 h, then at room temp. overnight, neutralized by aq. NaOH; ether layer separated, aq. phase extracted with Et2O, organic extracts dried over MgSO4, filtered, evapd. in vac., residue eluted through Al2O3 with hexane, second fraction collected, evaporated to dryness, recrystd.from hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2011.03.013

Reference yield:

: 4-(trans-4-n-penthylcyclohexyl)-2,3-difluorophenylboronicacid

: 1309378-27-5
4-bromophenyl[3]ferrocenophane

: 1309378-19-5
[Fe(C₅H₄)(C₅H₃C₆H₄C₆H₂F₂C₆H₁₀C₅H₁₁)(CH₂)3]

Guidance literature:: With Pd(PPh₃)4; Na₂CO₃; In water; toluene; soln. of Fe complex added to stirred mixt. of (HO)2BC6H2F2C6H10C5H11, Pd(PPh3)4 in toluene and aq. soln. of Na2CO3 (under Ar), refluxed for 3 d at stirring; extracted into Et2O, extracts washed with H2O, dried over MgSO4, solventevapd., eluted through Al2O3 with hexane;
DOI:10.1016/j.jorganchem.2011.03.013

Reference yield:

: 1309378-27-5
4-bromophenyl[3]ferrocenophane

: 4-(trans-4-n-decanecyclohexyl)-2,3-difluorophenylboronic acid

: 1309378-20-8
[Fe(C₅H₄)(C₅H₃C₆H₄C₆H₂F₂C₆H₁₀C₁₀H₂₁)(CH₂)3]

Guidance literature:: With Pd(PPh₃)4; Na₂CO₃; In water; toluene; soln. of Fe complex added to stirred mixt. of (HO)2BC6H2F2C6H10C10H21, Pd(PPh3)4 in toluene and aq. soln. of Na2CO3 (under Ar), refluxed for 3 dat stirring; extracted into Et2O, extracts washed with H2O, dried over MgSO4, solventevapd., eluted through Al2O3 with hexane;
DOI:10.1016/j.jorganchem.2011.03.013