1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane

Base Information

Chemical Name:1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane
CAS No.:104654-74-2
Molecular Formula:C₉H₁₄O₂
Molecular Weight:154.209
Hs Code.:
DSSTox Substance ID:DTXSID80545247
Mol file:104654-74-2.mol

Synonyms:104654-74-2;1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane;DTXSID80545247

Suppliers and Price of 1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane

Chemical Property:

XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:154.099379685
Heavy Atom Count:11
Complexity:186

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC2(CO2)C3(C1)COC3

Technology Process of 1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane

There total 5 articles about 1,6-Dioxadispiro[2.0.3~4~.4~3~]undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 104654-72-0
5-Methylene-2-oxa-spiro[3.5]nonane

: 104654-74-2
1,6-Dioxa-dispiro[2.0.3.4]undecane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1246/cl.1985.1785

Reference yield:

: 104654-69-5
Ethyl 2-methyl-1-cyclohex-1-ene carboxylate

: 104654-74-2
1,6-Dioxa-dispiro[2.0.3.4]undecane

Guidance literature:: Multi-step reaction with 5 steps

1: 79 percent / LDA / tetrahydrofuran / -78 °C

2: 80 percent / pyridine

3: 99 percent / LiAlH₄ / tetrahydrofuran / 1.5 h / Ambient temperature

4: 95 percent / NaH / tetrahydrofuran

5: 73 percent / m-chloroperoxybenzoic acid / CH₂Cl₂

With lithium aluminium tetrahydride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; pyridine; dichloromethane;
DOI:10.1246/cl.1985.1785

Reference yield:

: 104654-70-8
1-Hydroxymethyl-2-methylene-cyclohexanecarboxylic acid ethyl ester

: 104654-74-2
1,6-Dioxa-dispiro[2.0.3.4]undecane

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / pyridine

2: 99 percent / LiAlH₄ / tetrahydrofuran / 1.5 h / Ambient temperature

3: 95 percent / NaH / tetrahydrofuran

4: 73 percent / m-chloroperoxybenzoic acid / CH₂Cl₂

With lithium aluminium tetrahydride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; pyridine; dichloromethane;
DOI:10.1246/cl.1985.1785