Ni(SC(C₆H₅)2CH₂C₅H₃N)2

Base Information

• Chemical Name: Ni(SC(C₆H₅)2CH₂C₅H₃N)2
• CAS No.: 1234629-21-0
• Molecular Formula: C₃₈H₃₀N₂NiS₂
• Molecular Weight: 637.492
• Mol file: 1234629-21-0.mol

Synonyms:

Chemical Property of Ni(SC(C₆H₅)2CH₂C₅H₃N)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Ni(SC(C₆H₅)2CH₂C₅H₃N)2

There total 2 articles about Ni(SC(C₆H₅)2CH₂C₅H₃N)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[Ni(2,2'-(2,2'-bipyridine-6,6'-diyl)bis(1,1-diphenylethanethiolato))(imidazole)](1+) → (2,2'-(2,2'-bipyridine-6,6'-diyl)bis(1,1-diphenylethanethiolato))nickel(II) (1234629-21-0)

Guidance literature:

In not given; Electrochem. Process; redn. at -0.4 V vs Ag/Ag(1+);

DOI:10.1021/ic100945n

Reference yield:

C49H45FeN2NiOS2(1+)*BF4(1-) → Ni(SC(C6H5)2CH2C5H3N)2 (1234629-21-0) + C13H18FeNO

Guidance literature:

With tetrabutylammonium perchlorate; In acetonitrile; Kinetics; Electrolysis;

DOI:10.1021/acscatal.8b02830

Reference yield: 74.0%

Ni(SC(C6H5)2CH2C5H3N)2 (1234629-21-0) + water (7732-18-5) + methyl iodide (74-88-4) → NiCH3(SC(C6H5)2CH2C5H3N)2(1+)*I(1-)*H2O=NiCH3(SC(C6H5)2CH2C5H3N)2I*H2O

Guidance literature:

In dichloromethane; (Ar) CH3I was added to a suspn. of complex in CH2Cl2, the mixt. was stirred overnight; the solvent was removed under vac., extd. with an excess of CH3CN, vac-evapd., THF was added, stirred for a few min, ppt. was filtered, washed with THF, redissolved in min CH2Cl2, diethyl ether was allowed to slowly diffuse for 24 h; elem. anal.;

DOI:10.1021/ic200063d

Downstream raw materials:

[Ni(SC(C₆H₅)2CH₂(NC₅H₃)2CH₂C(C₆H₅)2SCH₃)]⁽¹⁺⁾*I^(1-)=[Ni(SC(C₆H₅)2CH₂(NC₅H₃)2CH₂C(C₆H₅)2SCH₃)]I