Methyl 1-phenylprop-2-yn-1-yl carbonate

Base Information

Chemical Name:Methyl 1-phenylprop-2-yn-1-yl carbonate
CAS No.:104846-76-6
Molecular Formula:C11H10O3
Molecular Weight:190.199
Hs Code.:
DSSTox Substance ID:DTXSID80544078
Nikkaji Number:J1.016.555E
Mol file:104846-76-6.mol

Synonyms:104846-76-6;Methyl 1-phenylprop-2-yn-1-yl carbonate;DTXSID80544078

Suppliers and Price of Methyl 1-phenylprop-2-yn-1-yl carbonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 1-phenylprop-2-yn-1-yl carbonate

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:190.062994177
Heavy Atom Count:14
Complexity:232

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)OC(C#C)C1=CC=CC=C1

Technology Process of Methyl 1-phenylprop-2-yn-1-yl carbonate

There total 3 articles about Methyl 1-phenylprop-2-yn-1-yl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 4187-87-5
1-Phenyl-2-propyn-1-ol

: 79-22-1
methyl chloroformate

: 104846-76-6
(±)-methyl (1-phenylprop-2-yn-1-yl) carbonate

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃;
DOI:10.1021/ol901964z

Reference yield:

: 100-52-7
benzaldehyde

: 104846-76-6
(±)-methyl (1-phenylprop-2-yn-1-yl) carbonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrahydrofuran / -20 - 20 °C / Inert atmosphere

1.2: 0 °C / Inert atmosphere

2.1: pyridine; dmap / dichloromethane / 20 °C / Inert atmosphere; Cooling

With pyridine; dmap; In tetrahydrofuran; dichloromethane;
DOI:10.1002/adsc.201401094