(4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside)

Base Information

Chemical Name:(4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside)
CAS No.:147821-48-5
Molecular Formula:C₂₁H₂₇NO₉S
Molecular Weight:469.513
Hs Code.:
DSSTox Substance ID:DTXSID701109935
Nikkaji Number:J650.612G
Wikidata:Q105113556

Synonyms:DTXSID701109935;(4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside);O-Methyl-4-[(2',3',4'-tri-O-acetyl-alpha-L-rhamnosyloxy)benzyl]thiocarbamate;[4-(2-O,3-O,4-O-Triacetyl-alpha-L-rhamnopyranosyloxy)benzyl]thiocarbamic acid O-methyl ester;147821-48-5;Carbamothioic acid, [[4-[(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)oxy]phenyl]methyl]-, O-methyl ester

Suppliers and Price of (4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside)

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:11
Exact Mass:469.14065261
Heavy Atom Count:32
Complexity:680

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1C(C(C(C(O1)OC2=CC=C(C=C2)CNC(=S)OC)OC(=O)C)OC(=O)C)OC(=O)C
Isomeric SMILES:C[C@H]1[C@@H]([C@H]([C@H]([C@@H](O1)OC2=CC=C(C=C2)CNC(=S)OC)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of (4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside)

There total 12 articles about (4-Methoxybenzyl)thiocarbamic acid 4'-O-(tri-O-acetyl-alpha-L-rhamnopyranoside) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 33148-47-9
4-allyloxy-benzonitrile

: 147821-48-5
N-methoxythiocarbonyl-4-(2',3',4'-tri-O-acetyl-α-L-rhamnopyranosyloxy)-benzylamine

Guidance literature:: Multi-step reaction with 6 steps

1: LiAlH₄ / diethyl ether / 24 h / Heating

2: Na₂CO₃ / acetone; H₂O / 2.5 h / Ambient temperature

3: 91 percent / HCOOH, PPh₃, Pd(OAc)2 / tetrahydrofuran / 4.5 h / Heating

4: 80 percent / NIS, MS, TfOH / CH₂Cl₂ / 2 h / -40 °C

5: H₂ / Pd / methanol / 6 h / Ambient temperature

6: dimethylformamide / 2 h / 80 °C

With palladium diacetate; N-iodo-succinimide; lithium aluminium tetrahydride; formic acid; trifluorormethanesulfonic acid; hydrogen; sodium carbonate; triphenylphosphine; palladium; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0008-6215(98)00223-7

Reference yield:

: 767-00-0
4-cyanophenol

: 147821-48-5
N-methoxythiocarbonyl-4-(2',3',4'-tri-O-acetyl-α-L-rhamnopyranosyloxy)-benzylamine

Guidance literature:: Multi-step reaction with 7 steps

1: NaH / dimethylformamide / 16 h / Ambient temperature

2: LiAlH₄ / diethyl ether / 24 h / Heating

3: Na₂CO₃ / acetone; H₂O / 2.5 h / Ambient temperature

4: 91 percent / HCOOH, PPh₃, Pd(OAc)2 / tetrahydrofuran / 4.5 h / Heating

5: 80 percent / NIS, MS, TfOH / CH₂Cl₂ / 2 h / -40 °C

6: H₂ / Pd / methanol / 6 h / Ambient temperature

7: dimethylformamide / 2 h / 80 °C

With palladium diacetate; N-iodo-succinimide; lithium aluminium tetrahydride; formic acid; trifluorormethanesulfonic acid; hydrogen; sodium hydride; sodium carbonate; triphenylphosphine; palladium; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0008-6215(98)00223-7

Reference yield:

: 75383-60-7
(4-hydroxy-benzyl)carbamic acid benzyl ester

: 147821-48-5
N-methoxythiocarbonyl-4-(2',3',4'-tri-O-acetyl-α-L-rhamnopyranosyloxy)-benzylamine

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / NIS, MS, TfOH / CH₂Cl₂ / 2 h / -40 °C

2: H₂ / Pd / methanol / 6 h / Ambient temperature

3: dimethylformamide / 2 h / 80 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; hydrogen; palladium; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(98)00223-7