33148-47-9

Basic information

• Product Name: 4-(allyloxy)benzonitrile
• Synonyms: 4-(allyloxy)benzonitrile
• CAS NO: 33148-47-9
• Molecular Formula: C₁₀H₉NO
• Molecular Weight: 159.18456
• Mol File: 33148-47-9.mol
• Article Data: 48

Chemical Properties

• Boiling Point: 288.8°Cat760mmHg
• Flash Point: 121.5°C
• Appearance: /
• Density: 1.05g/cm³
• Vapor Pressure: 0.00229mmHg at 25°C
• Refractive Index: 1.531
• Storage Temp.: Room temperature.
• CAS DataBase Reference: 4-(allyloxy)benzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(allyloxy)benzonitrile(33148-47-9)
• EPA Substance Registry System: 4-(allyloxy)benzonitrile(33148-47-9)

Safety Data

• Hazardous Substances Data: 33148-47-9(Hazardous Substances Data)

Usage

General Description

4-(allyloxy)benzonitrile is a chemical compound with the molecular formula C10H9NO. It is a white to light yellow crystalline solid that is commonly used in organic synthesis and as an intermediate in the production of various pharmaceuticals and agrochemicals. 4-(allyloxy)benzonitrile is known for its strong odor and is commonly used as a flavoring ingredient in the food industry. 4-(allyloxy)benzonitrile is considered to be a potentially hazardous chemical and should be handled with care, as exposure to this compound can cause irritation to the eyes, skin, and respiratory system. Additionally, it should be stored in a cool, dry place away from sources of ignition and incompatible substances.

InChI:InChI=1/C10H9NO/c1-2-7-12-10-5-3-9(8-11)4-6-10/h2-6H,1,7H2

Upstream product

• 767-00-0 4-cyanophenol 
• 106-95-6 allyl bromide 
• 1369862-32-7 1-(allyloxy)-4-(azidomethyl)benzene 
• 123-08-0 4-hydroxy-benzaldehyde 
• 5162-44-7 1-bromo-4-butene 
• 623-00-7 4-bromobenzenecarbonitrile 
• 107-18-6 allyl alcohol 
• 1065010-87-8 potassium cyclopropyltrifluoroborate 
• 1197-19-9 4-cyano-N,N-dimethylaniline 
• 3256-45-9 4-allyloxybenzyl alcohol 
• 106-41-2 4-bromo-phenol 
• 3328-57-2 sodium 4-cyanophenolate 
• 874-90-8 4-methoxybenzonitrile 
• 40663-68-1 4-(2-propenyloxy)benzaldehyde 

Downstream Products

• 90923-69-6 3-allyl-4-hydroxy-benzonitrile 
• 1026839-76-8 (5-{3-[4-(5-dimethylcarbamoyl-4-methyl-thiazol-2-yl)-2-propyl-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 1026423-85-7 (5-{3-[2-propyl-4-(4-trifluoromethyl-thiazol-2-yl)-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 1026124-03-7 (5-{3-[4-(5-acetyl-4-methyl-thiazol-2-yl)-2-propyl-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 1026030-90-9 (5-{3-[4-(4-ethoxy-5-methyl-thiazol-2-yl)-2-propyl-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 1027420-07-0 (5-{3-[4-(4-tert-butyl-thiazol-2-yl)-2-propyl-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 724467-27-0 ethyl ((1S)-5-{3-[4-(4-ethyl-1,3-thiazol-2-yl)-2-propylphenoxy]propoxy}-2,3-dihydro-1H-inden-1-yl)acetate 
• 1025831-61-1 (5-{3-[4-(4-ethoxy-thiazol-2-yl)-2-propyl-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 1026291-20-2 (5-{3-[4-(4-isopropoxy-thiazol-2-yl)-2-propyl-phenoxy]-propoxy}-indan-1-yl)-acetic acid ethyl ester 
• 724467-24-7 ethyl ((1S)-5-{3-[4-(aminocarbonothioyl)-2-propylphenoxy]propoxy}-2,3-dihydro-1H-inden-1-yl)acetic acid 
• 1027296-98-5 {5-[3-(2-propyl-4-thiazol-2-yl-phenoxy)-propoxy]-indan-1-yl}-acetic acid ethyl ester 
• 724467-23-6 {5-[3-(4-cyano-2-propyl-phenoxy)-propoxy]-indan-1-yl}-acetic acid ethyl ester 

Relevant articles and documents

Ion-imprinted polymer for selective separation of Cerium (III) ions from rare earth mixture

Ion-imprinting polymers (IIPs) materials draw the great recognition because of the powerful selectivity to the desired metal ions. Therefore, the ion-imprinting polymer (Ce-IIP) was prepared by using cerium metal with amidoxime ligand as the complexing agent, in addition ethylene glycol dimethacrylate (EGDMA) and 2,2-azobisisobutyronitrile (AIBN) are crosslinking agent and free radical initiator, respectively. Aqueous HCl was applied to leach the cerium ions from the imprinted polymer for the creation of cavities of template, which is utilized for further cerium ions adsorption with high selectivity. The Ce-IIP was characterized by using ICP-MS, FE-SEM and also solid state analysis by UV-vis NIR spectroscopy. FT-IR study confirmed the complexation of the Ce-IIP was successful. The optimum pH was found to be 6 and the highest adsorption capacity was estimated about 145 mg g-1. Thus, the prepared Ce-IIP gave very good selectivity to cerium ions in the presence of lanthanide ions and also Ce-IIP can be reused 10 times without a substantial loss in adsorption capacity.

Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes

An efficient and mild catalytic deallylation method of aryl allyl ethers is developed, with commercially available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process is compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway.

A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.