C₃₀H₄₄O₇Si₃

Base Information

• Chemical Name: C₃₀H₄₄O₇Si₃
• CAS No.: 1053715-06-2
• Molecular Formula: C₃₀H₄₄O₇Si₃
• Molecular Weight: 600.932
• Mol file: 1053715-06-2.mol

Synonyms:

Chemical Property of C₃₀H₄₄O₇Si₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of C₃₀H₄₄O₇Si₃

There total 13 articles about C₃₀H₄₄O₇Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzoyl chloride (98-88-4) → C30H44O7Si3 (1053715-06-2)

Guidance literature:

Multi-step reaction with 5 steps

1: pyridine; DMAP

2: NMO; OsO₄; H₂O / tetrahydrofuran / 20 °C

3: Zn; NH₄Cl; H₂O / tetrahydrofuran / Heating

4: dimethylformamide / 80 °C

5: Ph₂O / 0.25 h / Heating

With pyridine; dmap; osmium(VIII) oxide; N-methyl-2-indolinone; diphenylether; water; ammonium chloride; zinc; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Acylation / 2: Oxidation / 3: Ring cleavage / 4: Substitution / 5: Elimination;

DOI:10.1039/a905631i

Reference yield:

(+)-(1R,4S,4aR,5S,8aS)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one (194796-30-0) → C30H44O7Si3 (1053715-06-2)

Guidance literature:

Multi-step reaction with 12 steps

1: 89 percent / NaH / tetrahydrofuran / 20 °C

2: 82 percent / O₂; KF; (EtO)3P / dimethylsulfoxide

3: NaBH₄ / methanol; tetrahydrofuran / -15 °C

4: NBS / CH₂Cl₂ / -15 °C

5: 84 percent / POCl₃; pyridine / 50 °C

6: DIBAL-H / toluene / -78 °C

7: Bu₄NF / tetrahydrofuran / 20 °C

8: pyridine; DMAP

9: NMO; OsO₄; H₂O / tetrahydrofuran / 20 °C

10: Zn; NH₄Cl; H₂O / tetrahydrofuran / Heating

11: dimethylformamide / 80 °C

12: Ph₂O / 0.25 h / Heating

With pyridine; dmap; potassium fluoride; sodium tetrahydroborate; N-Bromosuccinimide; osmium(VIII) oxide; N-methyl-2-indolinone; diphenylether; tetrabutyl ammonium fluoride; water; oxygen; sodium hydride; diisobutylaluminium hydride; ammonium chloride; zinc; triethyl phosphite; trichlorophosphate; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; 1: Condensation / 2: Oxidation / 3: Reduction / 4: Bromination / 5: Dehydration / 6: Reduction / 7: desilylation / 8: Acylation / 9: Oxidation / 10: Ring cleavage / 11: Substitution / 12: Elimination;

DOI:10.1039/a905631i

Reference yield:

C12H15BrO3 (253589-88-7) → C30H44O7Si3 (1053715-06-2)

Guidance literature:

Multi-step reaction with 5 steps

1: pyridine; DMAP

2: NMO; OsO₄; H₂O / tetrahydrofuran / 20 °C

3: Zn; NH₄Cl; H₂O / tetrahydrofuran / Heating

4: dimethylformamide / 80 °C

5: Ph₂O / 0.25 h / Heating

With pyridine; dmap; osmium(VIII) oxide; N-methyl-2-indolinone; diphenylether; water; ammonium chloride; zinc; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Acylation / 2: Oxidation / 3: Ring cleavage / 4: Substitution / 5: Elimination;

DOI:10.1039/a905631i

upstream raw materials:

C₃₅H₅₀O₇Si₃

benzoyl chloride

(+)-(1R,4S,4aR,5S,8aS)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one

C₁₂H₁₅BrO₃

Downstream raw materials:

(+)-Pipoxide

(-)-Tonkinenin A

(-)-Uvarigranol G

((1R,2S,5R,6S)-5-(benzoyloxy)-1,2,6-trihydroxycyclohex-3-en-1-yl)methyl benzoate