diethylphosphorylacetic acid cinnamyl ester

Base Information

• Chemical Name: diethylphosphorylacetic acid cinnamyl ester
• CAS No.: 725725-87-1
• Molecular Formula: C₁₅H₂₁O₅P
• Molecular Weight: 312.303
• Mol file: 725725-87-1.mol

Synonyms:

Chemical Property of diethylphosphorylacetic acid cinnamyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethylphosphorylacetic acid cinnamyl ester

There total 1 articles about diethylphosphorylacetic acid cinnamyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

cinnamyl bromoacetate + triethyl phosphite (122-52-1) → diethylphosphorylacetic acid cinnamyl ester (725725-87-1)

Guidance literature:

In dichloromethane; for 70h; Heating;

DOI:10.1016/j.tetlet.2004.04.006

Reference yield:

1,2-bis(4-fluorophenyl)ethane-1,2-dione (579-39-5) + diethylphosphorylacetic acid cinnamyl ester (725725-87-1) → (E/Z)-3,4-bis-(4-fluoro-phenyl)-4-oxo-but-2-enoic acid cinnamyl ester

Guidance literature:

With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 2.5h;

DOI:10.1016/j.tetlet.2004.04.006

Reference yield:

benzil (134-81-6) + diethylphosphorylacetic acid cinnamyl ester (725725-87-1) → (E/Z)-4-oxo-3,4-diphenyl-but-2-enoic acid cinnamyl ester

Guidance literature:

With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 2.5h;

DOI:10.1016/j.tetlet.2004.04.006

upstream raw materials:

triethyl phosphite

Downstream raw materials:

Z-3-methyl-4-oxo-pent-2-enoic acid cinnamyl ester

E-3-methyl-4-oxo-pent-2-enoic acid cinnamyl ester