trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄OMe)2]

Base Information

• Chemical Name: trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄OMe)2]
• CAS No.: 1279129-63-3
• Molecular Formula: C₃₉H₃₄ClIrO₃P₂
• Molecular Weight: 840.318
• Mol file: 1279129-63-3.mol

Synonyms:

Chemical Property of trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄OMe)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄OMe)2]

There total 1 articles about trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄OMe)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

[IrCl(cyclooctene)2]2 (12246-51-4) + carbon monoxide (201230-82-2) + (2-methoxyphenyl)diphenylphosphine (53111-20-9) → trans-[Ir(CO)Cl(2-Ph2P-C6H4OMe)2] (1279129-63-3,61483-24-7)

Guidance literature:

In dichloromethane; acetonitrile; (Ir(COE)2Cl)2 dissolved in CH3CN, stirred at room temp. for 10 min underN2, N2 flow stopped, CO passed into soln. until clear greenish yellow s oln. obtained, soln. of 2-(Ph2P)-C6H4OCH3 in CH2Cl2 added, stirred for 30 min; evapn. under vac., residue washed with Et2O, recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1002/ejic.201001005

Reference yield:

trans-[Ir(CO)Cl(2-Ph2P-C6H4OMe)2] (1279129-63-3,61483-24-7) → trans-[Ir(O2)(CO)Cl(2-Ph2P-C6H4OMe)2]

Guidance literature:

With air; In toluene; solution cell, 4E-4M soln. of trans-(Ir(CO)Cl(2-Ph2PC6H4OMe)2) in toluene stirred in air at 25°C; not isolated; UV, IR; Kinetics;

DOI:10.1002/ejic.201001005

Reference yield:

trans-[Ir(CO)Cl(2-Ph2P-C6H4OMe)2] (1279129-63-3,61483-24-7) + iodine (7553-56-2,12190-71-5,8031-47-8) → [Ir(CO)ClI2(2-Ph2P-C6H4OMe)2] (1278584-44-3)

Guidance literature:

In dichloromethane; under N2; I2 added to soln. of trans-(Ir(CO)Cl(2-Ph2P-C6H4OMe)2) in CH2Cl2, mixt. stirred at room temp. for 2 h; evapn. under vac., residue washed with hexane; elem. anal.;

DOI:10.1002/ejic.201001005

upstream raw materials:

[IrCl(cyclooctene)₂]₂

carbon monoxide

(2-methoxyphenyl)diphenylphosphine

Downstream raw materials:

[Ir(CO)ClI₂(2-Ph₂P-C₆H₄OMe)2]

[Ir(CO)(CH₃)ClI(2-Ph₂P-C₆H₄OMe)2]