trimethylsilyl phenylmethylphosphinate

Base Information

• Chemical Name: trimethylsilyl phenylmethylphosphinate
• CAS No.: 99136-12-6
• Molecular Formula: C₁₀H₁₇O₂PSi
• Molecular Weight: 228.303
• Mol file: 99136-12-6.mol

Synonyms:

Chemical Property of trimethylsilyl phenylmethylphosphinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trimethylsilyl phenylmethylphosphinate

There total 1 articles about trimethylsilyl phenylmethylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

trimethylsilyl bromide (2857-97-8) + methyl methylphenylphosphinate (6389-79-3) → trimethylsilyl phenylmethylphosphinate (99136-12-6)

Guidance literature:

DOI:10.1016/0022-328X(85)80120-0

Reference yield:

rac-methyl(1-naphthyl)phenylchlorosilane (960-82-7,13132-42-8,51048-23-8,18142-87-5) + trimethylsilyl phenylmethylphosphinate (99136-12-6) → α-naphthylphenylmethylsilyl phenylmethylphosphinate

Guidance literature:

at 60 ℃; for 5h; under 0.01 Torr; removing the Me₃SiCl;

DOI:10.1016/0022-328X(85)80120-0

Reference yield:

trimethylsilyl phenylmethylphosphinate (99136-12-6) + diphenyl(α-naphthylphenylmethylsilyl)phosphate (81041-84-1) → diphenyl(trimethylsilyl)phosphate (25723-74-4) + α-naphthylphenylmethylsilyl phenylmethylphosphinate

Guidance literature:

In tetrachloromethane; equilibrium; 31P NMR;

DOI:10.1016/0022-328X(85)80120-0

upstream raw materials:

trimethylsilyl bromide

methyl methylphenylphosphinate

Downstream raw materials:

diphenyl(trimethylsilyl)phosphate