(3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

Base Information

Chemical Name:(3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one
CAS No.:118993-49-0
Molecular Formula:C₁₄H₁₄O₅
Molecular Weight:262.262
Hs Code.:

(3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo<d>-1,3-dioxol-2-one

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Suppliers and Price of (3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

Chemical Property:

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Technology Process of (3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

There total 4 articles about (3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 119043-06-0,130697-65-3,130790-30-6
(3aα,6α,7α,7aα)-6,7-epoxy-3a,6,7,7a-tetrahydrobenzo-1,3-dioxol-2-one

: 100-51-6,185532-71-2
benzyl alcohol

: 118993-49-0,130633-13-5
(3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; for 23.5h; Ambient temperature;

Reference yield:

: 17793-95-2
cis-1,2-dihydrocatechol

: 118993-49-0,130633-13-5
(3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 65 percent / triethylamine / CH₂Cl₂; toluene / -30 - 25 °C

2: m-chloroperbenzoic acid / CH₂Cl₂ / 0 - 25 °C

3: 85 percent / camphorsulphonic acid / CH₂Cl₂

With triethylamine; 3-chloro-benzenecarboperoxoic acid; camphor-10-sulfonic acid; In dichloromethane; toluene;
DOI:10.1016/S0040-4039(00)80744-3

Reference yield:

: 118993-48-9
(3aS,7aR)-3a,7a-Dihydro-benzo[1,3]dioxol-2-one

: 118993-49-0,130633-13-5
(3aα,6β,7α,7aα)-6-(benzyloxy)-3a,6,7,7a-tetrahydro-7-hydroxybenzo-1,3-dioxol-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: m-chloroperbenzoic acid / CH₂Cl₂ / 0 - 25 °C

2: 85 percent / camphorsulphonic acid / CH₂Cl₂

With 3-chloro-benzenecarboperoxoic acid; camphor-10-sulfonic acid; In dichloromethane;
DOI:10.1016/S0040-4039(00)80744-3