Dilithium benzophenone dianion

Base Information

• Chemical Name: Dilithium benzophenone dianion
• CAS No.: 15697-31-1
• Molecular Formula: C₁₃H₁₀O*2Li
• Molecular Weight: 196.104
• Mol file: 15697-31-1.mol

Synonyms:

Chemical Property of Dilithium benzophenone dianion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dilithium benzophenone dianion

There total 4 articles about Dilithium benzophenone dianion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

benzophenone (119-61-9) → lithium diphenylcarbinolate (2036-66-0,15697-31-1)

Guidance literature:

With [{(DipNPPh₂)Li}4(LiH)4]; In benzene; at 20 ℃; for 4h; Inert atmosphere;

DOI:10.1002/anie.201108134

Reference yield:

1,1-Diphenylmethanol (91-01-0) → lithium diphenylcarbinolate (2036-66-0,15697-31-1)

Guidance literature:

With lithium hexamethyldisilazane; In tetrahydrofuran; at 25 ℃; Thermodynamic data; ΔH_dep;

Reference yield:

diethyl sulphide (70-29-1) + dodecamethylcyclohexasilane (4098-30-0) → Dilithium benzophenone dianion (2036-66-0,15697-31-1)

Guidance literature:

In 1,4-dioxane; decane; Mechanism; Irradiation; competition reaction with other sulfoxides with photochemically generated dimethylsilylene;

DOI:10.1016/S0022-328X(00)98504-8

upstream raw materials:

1,1-Diphenylmethanol

diethyl sulphide

dodecamethylcyclohexasilane

benzophenone

Downstream raw materials:

1,1-Diphenylmethanol

benzophenone

oxido-diphenyl-methanide

1,1-diphenylpentanol