glycyl>trifluoroacetic anhydride

Base Information

• Chemical Name: glycyl>trifluoroacetic anhydride
• CAS No.: 77409-72-4
• Molecular Formula: C₁₃H₇F₆NO₆
• Molecular Weight: 387.192
• Mol file: 77409-72-4.mol

Synonyms:

Chemical Property of glycyl>trifluoroacetic anhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of glycyl>trifluoroacetic anhydride

There total 1 articles about glycyl>trifluoroacetic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Salicyluric acid (487-54-7) + trifluoroacetic anhydride (407-25-0) → glycyl>trifluoroacetic anhydride (77409-72-4)

Guidance literature:

In dichloromethane; at 50 ℃; for 2h;

DOI:10.1021/jo01297a008

Reference yield:

N1,N8-Bis<2,3-(methylenedioxy)benzoyl>spermidine (76927-61-2) + glycyl>trifluoroacetic anhydride (77409-72-4) → N4--N1,N8-bis<2,3-(methylenedioxy)benzoyl>spermidine (76927-63-4)

Guidance literature:

With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; In dichloromethane; Yield given; 1.) -78 deg C; 2.) room temp., 45 h;

DOI:10.1021/jo00331a026

Reference yield:

N1,N8-bis(benzoyl)spermidine acetate (73038-12-7) + glycyl>trifluoroacetic anhydride (77409-72-4) → N4--N1,N8-bis(benzoyl)spermidine (73038-08-1)

Guidance literature:

With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; In dichloromethane; Yield given; 1.) -78 deg C, 2.) 30h RT;

DOI:10.1021/jo01297a008

upstream raw materials:

Salicyluric acid

trifluoroacetic anhydride

Downstream raw materials:

N⁴--N¹,N⁸-bis<2,3-(methylenedioxy)benzoyl>spermidine

N⁴--N¹,N⁸-bis(benzoyl)spermidine

3-<(2,3-dihydroxybenzoylamino)propyl>-N-<4-(2,3-dihydroxy-benzoylamino)butyl>-2-hydroxybenzoyl-glycylamide