{1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

Base Information

Chemical Name:{1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane
CAS No.:192565-68-7
Molecular Formula:C₃₇H₅₀O₅SSi
Molecular Weight:634.952
Hs Code.:

{1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

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Chemical Property of {1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

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Technology Process of {1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

There total 7 articles about {1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 192565-69-8
1-deoxy-3,5-di-O-benzyl-2-O-(3,3-dimethyl-2-oxobutyl)-1-phenylsulfenyl-D-xylofuranose

: 192565-68-7
{1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/S0040-4020(99)00959-X

Reference yield:

: 41341-99-5
3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose

: 192565-68-7
{1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.08 g / conc. H₂SO₄ / acetonitrile; H₂O / 35 °C

2: 1.049 g / Bu₃P / CH₂Cl₂ / 15.5 h / 0 - 20 °C

3: 88 percent / Aliquat 336; aq. NaOH / CH₂Cl₂ / 1 h / 20 °C

4: Et₃N / CH₂Cl₂ / 0 - 20 °C

With sodium hydroxide; tributylphosphine; sulfuric acid; Aliquat 336; triethylamine; In dichloromethane; water; acetonitrile; 1: Hydrolysis / 2: Substitution / 3: Etherification / 4: Etherification;
DOI:10.1016/S0040-4020(99)00959-X

Reference yield:

: 16054-77-6,120693-82-5,120693-83-6
3,5-di-O-benzyl-D-xylofuranose

: 192565-68-7
{1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.049 g / Bu₃P / CH₂Cl₂ / 15.5 h / 0 - 20 °C

2: 88 percent / Aliquat 336; aq. NaOH / CH₂Cl₂ / 1 h / 20 °C

3: Et₃N / CH₂Cl₂ / 0 - 20 °C

With sodium hydroxide; tributylphosphine; Aliquat 336; triethylamine; In dichloromethane; 1: Substitution / 2: Etherification / 3: Etherification;
DOI:10.1016/S0040-4020(99)00959-X