1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene

Base Information

Chemical Name:1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene
CAS No.:158555-82-9
Molecular Formula:C₃₃H₄₅NO₃SeSi
Molecular Weight:610.771
Hs Code.:

1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-<N-(benzyloxycarbonyl)-N-<2-(phenylseleno)ethyl>amino>propyl>benzene

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene

Chemical Property:

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Technology Process of 1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene

There total 6 articles about 1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13037-83-7
4-allyl-2,6-dimethylphenol

: 158555-82-9
1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene

Guidance literature:: Multi-step reaction with 5 steps

1: 86 percent / imidazole / dimethylformamide / 4 h / Ambient temperature

2: 1.) BH₃*THF, 2.) 30percent H₂O₂, 3 N NaOH / 1.) THF, 0 deg C, 10 min; 2 h, 2.) 0 deg C, 15 min; 1 h

3: 58 percent / PDC / CH₂Cl₂ / 20 h / Ambient temperature

4: 1.) MgSO₄, 2.) NaBH₄ / 1.) CH₂Cl₂, 0 deg C, 2 h, 2.) CH₃OH, 0 deg C, 30 min

5: aq. NaHCO₃ / CH₂Cl₂ / 8 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; sodium tetrahydroborate; dipyridinium dichromate; borane-THF; dihydrogen peroxide; sodium hydrogencarbonate; magnesium sulfate; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo00100a039

Reference yield:

: 118630-96-9
1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-(2-propenyl)benzene

: 158555-82-9
1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) BH₃*THF, 2.) 30percent H₂O₂, 3 N NaOH / 1.) THF, 0 deg C, 10 min; 2 h, 2.) 0 deg C, 15 min; 1 h

2: 58 percent / PDC / CH₂Cl₂ / 20 h / Ambient temperature

3: 1.) MgSO₄, 2.) NaBH₄ / 1.) CH₂Cl₂, 0 deg C, 2 h, 2.) CH₃OH, 0 deg C, 30 min

4: aq. NaHCO₃ / CH₂Cl₂ / 8 h / Ambient temperature

With sodium hydroxide; sodium tetrahydroborate; dipyridinium dichromate; borane-THF; dihydrogen peroxide; sodium hydrogencarbonate; magnesium sulfate; In dichloromethane;
DOI:10.1021/jo00100a039

Reference yield:

: 118631-05-3
3-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-propanol

: 158555-82-9
1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethyl-4-<3-amino>propyl>benzene

Guidance literature:: Multi-step reaction with 3 steps

1: 58 percent / PDC / CH₂Cl₂ / 20 h / Ambient temperature

2: 1.) MgSO₄, 2.) NaBH₄ / 1.) CH₂Cl₂, 0 deg C, 2 h, 2.) CH₃OH, 0 deg C, 30 min

3: aq. NaHCO₃ / CH₂Cl₂ / 8 h / Ambient temperature

With sodium tetrahydroborate; dipyridinium dichromate; sodium hydrogencarbonate; magnesium sulfate; In dichloromethane;
DOI:10.1021/jo00100a039