Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2⁽¹⁺⁾*ClO₄^(1-)=Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2ClO₄

Base Information

• Chemical Name: Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2⁽¹⁺⁾*ClO₄^(1-)=Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2ClO₄
• CAS No.: 1137141-49-1
• Molecular Formula: C₄₆H₇₂N₇Ni₂O₂S₂*ClO₄
• Molecular Weight: 1036.09
• Mol file: 1137141-49-1.mol

Synonyms:

Chemical Property of Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2⁽¹⁺⁾*ClO₄^(1-)=Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2⁽¹⁺⁾*ClO₄^(1-)=Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2ClO₄

There total 1 articles about Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2⁽¹⁺⁾*ClO₄^(1-)=Ni₂(O₂CNHCH₂C₆H₅)(NCH₃)6(CH₂)12(C₆H₂SC(CH₃)3)2ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

lithium perchlorate trihydrate + [(-CH2C6H2(S)(tert-butyl)CH2N(methyl)C2H4N(methyl)C2H4N(methyl)CH2C6H2(S)(tert-butyl)CH2N(methyl)C2H4N(methyl)C2H4N(methyl)-)Ni2(μ-Cl)](perchlorate) (366804-74-2) + carbon dioxide (124-38-9,18923-20-1) + benzylamine (100-46-9) → Ni2(O2CNHCH2C6H5)(NCH3)6(CH2)12(C6H2SC(CH3)3)2(1+)*ClO4(1-)=Ni2(O2CNHCH2C6H5)(NCH3)6(CH2)12(C6H2SC(CH3)3)2ClO4 (1137141-49-1)

Guidance literature:

In ethanol; acetonitrile; soln. of Ni-complex and benzylamine in MeCN stirred for 1 d under CO2 atm., LiClO4*3H2O in EtOH added; concd. in vacuo, filtered, washed with cold EtOH, dried in air, recrystd. from MeCN/EtOH; elem. anal.;

DOI:10.1016/j.ica.2008.03.016

upstream raw materials:

[(-CH₂C₆H₂(S)(tert-butyl)CH₂N(methyl)C₂H₄N(methyl)C₂H₄N(methyl)CH₂C₆H₂(S)(tert-butyl)CH₂N(methyl)C₂H₄N(methyl)C₂H₄N(methyl)-)Ni₂(μ-Cl)](perchlorate)

carbon dioxide

benzylamine