dibenzo[b,f]selenepine

Base Information

• Chemical Name: dibenzo[b,f]selenepine
• CAS No.: 25049-13-2
• Molecular Formula: C₁₄H₁₀Se
• Molecular Weight: 257.193
• Mol file: 25049-13-2.mol

Synonyms:

Chemical Property of dibenzo[b,f]selenepine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibenzo[b,f]selenepine

There total 2 articles about dibenzo[b,f]selenepine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

bis(ortho-formyl-phenyl)selenide (124393-13-1) → dibenzo[b,f]selenepine (25049-13-2)

Guidance literature:

With pyridine; titanium tetrachloride; zinc; In tetrahydrofuran; at 0 ℃; Inert atmosphere; Reflux;

DOI:10.1021/ol401225n

Reference yield:

→ dibenzo[b,f]selenepine (25049-13-2)

Guidance literature:

10-Chlor-10,11-dihydrodibenzoselenepin, sd.CHCl3, 1-Methylpiperazin; neben anderen Verb.;

Reference yield:

dibenzo[b,f]selenepine (25049-13-2) → 10,11-dihydrodibenzo[b,f]selenepin-10-ol (25574-28-1) + 5,6-dihydrodibenzoselenepin

Guidance literature:

Multi-step reaction with 2 steps

1: dimethylsulfide borane complex / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

2: sodium hydroxide; sodium perborate monohydrate / tetrahydrofuran; water / 20 °C

With sodium perborate monohydrate; dimethylsulfide borane complex; sodium hydroxide; In tetrahydrofuran; water;

DOI:10.1021/ol401225n

upstream raw materials:

bis(ortho-formyl-phenyl)selenide

Downstream raw materials:

10,11-dihydrodibenzo[b,f]selenepin-10-ol