Bis(o-formylphenyl)selenide

Base Information

• Chemical Name: Bis(o-formylphenyl)selenide
• CAS No.: 124393-13-1
• Molecular Formula: C14H10O2Se
• Molecular Weight: 289.192
• DSSTox Substance ID: DTXSID60556179
• Nikkaji Number: J1.081.516I
• Wikidata: Q82437667
• Mol file: 124393-13-1.mol

Synonyms:bis(o-formylphenyl)selenide;124393-13-1;2,2'-Selanyldibenzaldehyde;DTXSID60556179

Chemical Property of Bis(o-formylphenyl)selenide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 289.98460
• Heavy Atom Count: 17
• Complexity: 241

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C=O)[Se]C2=CC=CC=C2C=O

Technology Process of Bis(o-formylphenyl)selenide

There total 7 articles about Bis(o-formylphenyl)selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

bis(o-formylphenyl) selenide acetal (343630-11-5) → bis(ortho-formyl-phenyl)selenide (124393-13-1)

Guidance literature:

With hydrogenchloride; In methanol; tetrachloromethane; for 2h; Heating;

DOI:10.1016/S0022-328X(00)00830-5

Reference yield: 34.0%

2-formylbenzene boronic acid (40138-16-7) → bis(ortho-formyl-phenyl)selenide (124393-13-1)

Guidance literature:

With selenium; copper(l) iodide; 1,10-Phenanthroline; ammonium tetrafluoroborate; In water; dimethyl sulfoxide; at 100 ℃; for 36h;

DOI:10.1016/j.tet.2016.08.012

Reference yield: 6.0%

2-chloro-benzaldehyde (89-98-5) → bis(ortho-formylphenyl)dimethyl selenide (27513-89-9) + bis(ortho-formyl-phenyl)selenide (124393-13-1)

Guidance literature:

With dilithium diselenide; In N,N,N,N,N,N-hexamethylphosphoric triamide; 1.) R_.T_., 18 h, 2.) 120 deg C, 6 h;

DOI:10.1016/S0040-4020(01)89801-X

upstream raw materials:

2-chloro-benzaldehyde

bis(o-formylphenyl) selenide acetal

2-(2-bromophenyl)-1,3-dioxolan

2-methylphenyl bromide

Downstream raw materials:

bis[o-(((2,6-diisopropylphenyl)imino)methyl)phenyl]selenide

10,11-dihydrodibenzo[b,f]selenepin-10-ol

dibenzo[b,f]selenepine