(S)-(+)-2-octyl phenyl selenide

Base Information

• Chemical Name: (S)-(+)-2-octyl phenyl selenide
• CAS No.: 75808-97-8
• Molecular Formula: C₁₄H₂₂Se
• Molecular Weight: 269.289
• Mol file: 75808-97-8.mol

Synonyms:

Chemical Property of (S)-(+)-2-octyl phenyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-(+)-2-octyl phenyl selenide

There total 3 articles about (S)-(+)-2-octyl phenyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl selenocyanate (2179-79-5) + (R)-Octan-2-ol (5978-70-1,113301-48-7,4128-32-9) → ((R)-1-Methyl-heptylselanyl)-benzene + (S)-(+)-2-octyl phenyl selenide (75808-97-8)

Guidance literature:

With tributylphosphine; In tetrahydrofuran; at 20 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1039/c39800000656

Reference yield:

diphenyl diselenide (1666-13-3) + (R)-2-octyl diphenylphosphinite (5740-26-1,5764-46-5,63543-81-7) → (S)-(+)-2-octyl phenyl selenide (75808-97-8)

Guidance literature:

With indium; In dichloromethane; Reflux; Inert atmosphere;

DOI:10.5012/bkcs.2011.32.6.1847

Reference yield:

(S)-2-Octanol (6169-06-8,113301-48-7,4128-32-9) + sodium phenylselenide (23974-72-3) → ((R)-1-Methyl-heptylselanyl)-benzene + (S)-(+)-2-octyl phenyl selenide (75808-97-8)

Guidance literature:

With methanesulfonyl chloride; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1) Et₂O, 0 deg C, 2) THF, HMPA, 20 deg C;

DOI:10.1039/c39800000656

upstream raw materials:

phenyl selenocyanate

(R)-Octan-2-ol

(S)-2-Octanol

sodium phenylselenide

Downstream raw materials:

(S)-(+)-2-bromooctane

(2R)-2-bromooctane