(η4-dipentene)PtCl2

Base Information

• Chemical Name: (η4-dipentene)PtCl2
• CAS No.: 12288-31-2
• Molecular Formula: C₁₀H₁₆Cl₂Pt
• Molecular Weight: 402.223
• Mol file: 12288-31-2.mol

Synonyms:

Chemical Property of (η4-dipentene)PtCl2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (η4-dipentene)PtCl2

There total 1 articles about (η4-dipentene)PtCl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η4-4-vinylcyclohexene)PtCl2 (12145-50-5,33594-03-5) + limonene. (138-86-3,555-08-8,8022-90-0,9003-73-0,95327-98-3) → (η4-dipentene)PtCl2 (12288-31-2,12288-32-3,12084-60-5,944820-66-0) + 4-ethenylcyclohexene (100-40-3)

Guidance literature:

In chloroform-d1; slight excess of the diolefine was added to a CDCl3 coln. of Pt-complex, reaction was followed by (1)H NMR until equil. was reached; products were identified by their (1)H NMR spectra;

DOI:10.1021/om00149a015

Reference yield:

(η4-dipentene)PtCl2 (12288-31-2,12288-32-3,12084-60-5,944820-66-0) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + limonene. (138-86-3,555-08-8,8022-90-0,9003-73-0,95327-98-3)

Guidance literature:

In chloroform-d1; slight excess of the diolefine was added to a CDCl3 coln. of Pt-complex, reaction was followed by (1)H NMR until equil. was reached; products were identified by their (1)H NMR spectra;

DOI:10.1021/om00149a015

Reference yield:

(η4-dipentene)PtCl2 (12288-31-2,12288-32-3,12084-60-5,944820-66-0) + bi(cyclopentadiene) (77-73-6,933-60-8,1755-01-7,25038-78-2) → (dicyclopentadiene)platinum(II) dichloride (12083-92-0) + limonene. (138-86-3,555-08-8,8022-90-0,9003-73-0,95327-98-3)

Guidance literature:

In chloroform-d1; slight excess of the diolefine was added to a CDCl3 coln. of Pt-complex, reaction was followed by (1)H NMR until equil. was reached; products were identified by their (1)H NMR spectra;

DOI:10.1021/om00149a015

upstream raw materials:

(η4-4-vinylcyclohexene)PtCl2

limonene.

Downstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

limonene.

(dicyclopentadiene)platinum(II) dichloride