(2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Base Information

Chemical Name:(2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene
CAS No.:162428-06-0
Molecular Formula:C₄₇H₈₆N₄O₁₁Si₂
Molecular Weight:939.391
Hs Code.:

(2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Synonyms:

Suppliers and Price of (2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

There total 9 articles about (2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 162428-06-0
(2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Guidance literature:: Multi-step reaction with 5 steps

1: imidazole / dimethylformamide / 1 h / Ambient temperature

2: molecular sieves (4 Angstroem), pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

3: 1M diisopropylaluminium hydride / toluene / 0.33 h / Ambient temperature

4: triphenylphosphane / tetrahydrofuran; H₂O / 5 h / 60 °C

5: propan-2-ol / 120 h / 120 °C

With 1H-imidazole; diisopropyl aluminum hydride; 4 A molecular sieve; triphenylphosphine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol; toluene;

Reference yield:

: (1S,2S,3R,6R)-6-Azido-4-hydroxymethyl-cyclohex-4-ene-1,2,3-triol

: 162428-06-0
(2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Guidance literature:: Multi-step reaction with 8 steps

1: p-toluenesulfonic acid monohydrate / dimethylformamide / 2 h / 55 °C

2: diisopropylethylamine / CH₂Cl₂ / 12 h / Heating

3: aq. 80percent acetic acid / 1 h / 60 °C

4: imidazole / dimethylformamide / 1 h / Ambient temperature

5: molecular sieves (4 Angstroem), pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

6: 1M diisopropylaluminium hydride / toluene / 0.33 h / Ambient temperature

7: triphenylphosphane / tetrahydrofuran; H₂O / 5 h / 60 °C

8: propan-2-ol / 120 h / 120 °C

With 1H-imidazole; diisopropyl aluminum hydride; 4 A molecular sieve; toluene-4-sulfonic acid; acetic acid; N-ethyl-N,N-diisopropylamine; triphenylphosphine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol; toluene;

Reference yield:

: 1-azido-1-deoxy-2,3:4,6-O-isopropylidene-5a-carba-β-D-xylo-hex-5(5a)-enopyranose

: 162428-06-0
(2S,3R,4Z)-1-<6-O-tert-butyldimethylsilyl-2,3-di-O-methoxymethyl-5a-carba-α-L-arabino-hex-5(5a)-enopyranosylamino>-3-tert-butyldimethylsilyloxy-2-(2,4-dinitrophenyl)amino-4-octadecene

Guidance literature:: Multi-step reaction with 9 steps

1: aq. 80percent acetic acid / 0.67 h / 70 °C

2: p-toluenesulfonic acid monohydrate / dimethylformamide / 2 h / 55 °C

3: diisopropylethylamine / CH₂Cl₂ / 12 h / Heating

4: aq. 80percent acetic acid / 1 h / 60 °C

5: imidazole / dimethylformamide / 1 h / Ambient temperature

6: molecular sieves (4 Angstroem), pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

7: 1M diisopropylaluminium hydride / toluene / 0.33 h / Ambient temperature

8: triphenylphosphane / tetrahydrofuran; H₂O / 5 h / 60 °C

9: propan-2-ol / 120 h / 120 °C

With 1H-imidazole; diisopropyl aluminum hydride; 4 A molecular sieve; toluene-4-sulfonic acid; acetic acid; N-ethyl-N,N-diisopropylamine; triphenylphosphine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol; toluene;