Technology Process of N,N'-bis(1,1,3-trimethyl-3-phenylbutyl)thiadiaziridine 1,1-dioxide
There total 4 articles about N,N'-bis(1,1,3-trimethyl-3-phenylbutyl)thiadiaziridine 1,1-dioxide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 75 percent / H2SO4 / acetic acid / 12 h / Ambient temperature
2: 84 percent / aq. KOH / 24 h / 200 °C
3: 55 percent / triethylamine, sulfuryl chloride / CH2Cl2 / 4 h / -10 °C
4: 1.) sodium hydride, 2.) tert-butyl hypochlorite / 1.) hexane, reflux, 2 h, 2.) a) -30 deg C, 3 h, b) 0 deg C, 1 h
With
sulfuryl dichloride; tert-butylhypochlorite; sulfuric acid; sodium hydride; triethylamine;
In
potassium hydroxide; dichloromethane; acetic acid;
DOI:10.1021/jo00323a021
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 55 percent / triethylamine, sulfuryl chloride / CH2Cl2 / 4 h / -10 °C
2: 1.) sodium hydride, 2.) tert-butyl hypochlorite / 1.) hexane, reflux, 2 h, 2.) a) -30 deg C, 3 h, b) 0 deg C, 1 h
With
sulfuryl dichloride; tert-butylhypochlorite; sodium hydride; triethylamine;
In
dichloromethane;
DOI:10.1021/jo00323a021
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 84 percent / aq. KOH / 24 h / 200 °C
2: 55 percent / triethylamine, sulfuryl chloride / CH2Cl2 / 4 h / -10 °C
3: 1.) sodium hydride, 2.) tert-butyl hypochlorite / 1.) hexane, reflux, 2 h, 2.) a) -30 deg C, 3 h, b) 0 deg C, 1 h
With
sulfuryl dichloride; tert-butylhypochlorite; sodium hydride; triethylamine;
In
potassium hydroxide; dichloromethane;
DOI:10.1021/jo00323a021
