aquapentaammineruthenium(III)

Base Information

• Chemical Name: aquapentaammineruthenium(III)
• CAS No.: 25590-52-7
• Molecular Formula: H₁₇N₅ORu
• Molecular Weight: 204.238
• Mol file: 25590-52-7.mol

Synonyms:

Chemical Property of aquapentaammineruthenium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of aquapentaammineruthenium(III)

There total 5 articles about aquapentaammineruthenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ru(2+)*5NH3=Ru(NH3)5(2+) → hexaammineruthenium(III) (18943-33-4) + pentaammine ruthenium(III) chloride (21560-19-0) + aquapentaammineruthenium(III) (25590-52-7) + {Ru(NH3)5(OH)}(2+) (21393-88-4)

Guidance literature:

With hydrogen cation; sodium chloride; In water; byproducts: Co(2+), NH4(1+), I(1-); oxidation with (CoI(NH3)5)(2+) in NaCl soln. at pH <5; formation of a mixt. of (RuCl(NH3)5)(2+), (RuH2O(NH3)5)(3+), (RuOH(NH3)5)(2+) and (Ru(NH3)6)(3+) with (RuCl(NH3)5)(2+) as main product;;

DOI:10.1021/ja01063a008

Reference yield:

Ru(2+)*5NH3=Ru(NH3)5(2+) → hexaammineruthenium(III) (18943-33-4) + pentaammine ruthenium(III) chloride (21560-19-0) + aquapentaammineruthenium(III) (25590-52-7)

Guidance literature:

With perchlorate^(1-); hydrogen cation; sodium chloride; In water; byproducts: H2O, Cl(1-); oxidation by ClO4(1-) in acidic 0.142 m-NaCl soln.;; formation of (RuH2O(NH3)5)(3+) and (Ru(NH3)6)(3+) as by-products;; Kinetics;

DOI:10.1021/ja00883a076

Reference yield:

azidepentaamminecobalt(III)(2+) (14403-83-9) + aquapentaammineruthenium(II)(2+) (21393-88-4) → aquapentaammineruthenium(III) (25590-52-7) + cobalt(II) (22541-53-3,65860-59-5)

Guidance literature:

In hydrogenchloride; byproducts: N3(1-), NH3; 25°C, I = 0.20 M (LiCl); not isolated, reaction followed by UV/VIS spectroscopy; Kinetics;

DOI:10.1039/DT9780000148

upstream raw materials:

azidepentaamminecobalt(III)⁽²⁺⁾

aquapentaammineruthenium(II)⁽²⁺⁾

Downstream raw materials:

pentaammine ruthenium(III) chloride

bromide

iodide