pentaamminechlororuthenium

Base Information

• Chemical Name: pentaamminechlororuthenium
• CAS No.: 21560-19-0
• Molecular Formula: ClH₁₅N₅Ru
• Molecular Weight: 221.676
• Mol file: 21560-19-0.mol

Synonyms:Ruthenium(2+),pentaamminechloro-, ion (8CI); Chloropentaammineruthenium(2+);Pentaamminechlororuthenium(2+)

Chemical Property of pentaamminechlororuthenium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 130.10000
• Density: g/cm³
• LogP: 1.23800

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of pentaamminechlororuthenium

There total 7 articles about pentaamminechlororuthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexaamineruthenium(II) (19052-44-9) → pentaammine ruthenium(III) chloride (21560-19-0)

Guidance literature:

With perchlorate^(1-); Sulfate; In sulfuric acid; oxidation with ClO4(1-) in a SO4(2-)-H2SO4-reaction medium (pH 2.8) at 25 °C, ionic strength 0.62 mol/l;; main product (RuCl(NH3)5)(2+); react. conditions minimize spontaneous decompn. of (Ru(NH3)6)(2+);; Kinetics;

DOI:10.1021/ja00883a076

Reference yield:

Ru(2+)*5NH3=Ru(NH3)5(2+) → hexaammineruthenium(III) (18943-33-4) + pentaammine ruthenium(III) chloride (21560-19-0) + aquapentaammineruthenium(III) (25590-52-7) + {Ru(NH3)5(OH)}(2+) (21393-88-4)

Guidance literature:

With hydrogen cation; sodium chloride; In water; byproducts: Co(2+), NH4(1+), I(1-); oxidation with (CoI(NH3)5)(2+) in NaCl soln. at pH <5; formation of a mixt. of (RuCl(NH3)5)(2+), (RuH2O(NH3)5)(3+), (RuOH(NH3)5)(2+) and (Ru(NH3)6)(3+) with (RuCl(NH3)5)(2+) as main product;;

DOI:10.1021/ja01063a008

Reference yield:

Ru(2+)*5NH3=Ru(NH3)5(2+) → hexaammineruthenium(III) (18943-33-4) + pentaammine ruthenium(III) chloride (21560-19-0) + aquapentaammineruthenium(III) (25590-52-7)

Guidance literature:

With perchlorate^(1-); hydrogen cation; sodium chloride; In water; byproducts: H2O, Cl(1-); oxidation by ClO4(1-) in acidic 0.142 m-NaCl soln.;; formation of (RuH2O(NH3)5)(3+) and (Ru(NH3)6)(3+) as by-products;; Kinetics;

DOI:10.1021/ja00883a076

upstream raw materials:

hydrogenchloride

{Ru(NH₃)5(OH)}⁽²⁺⁾

aquapentaammineruthenium(III)

sodium chloride