dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium

Base Information

• Chemical Name: dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium
• CAS No.: 122114-08-3
• Molecular Formula: C₂₇H₂₁CrO₃P
• Molecular Weight: 476.432
• Mol file: 122114-08-3.mol

Synonyms:

Chemical Property of dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium

There total 2 articles about dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

[(1,2,3,4,5,6-η)benzaldehyde]tricarbonylchromium (12170-15-9) + triphenylphosphine (603-35-0) → dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium (122114-08-3)

Guidance literature:

In benzene; Irradiation (UV/VIS); N2-atmosphere; irradiation of mixt. of PPh3 and slight excess of Cr-complex (medium pressure Hg-lamp) for 8 h; filtration, flash chromy. (SiO2, hexanes/CH2Cl2=1:1);

DOI:10.1016/0022-328X(95)05964-Q

Reference yield:

dioxolanebenzaldehyde chromium dicarbonyl triphenylphosphine (122120-90-5) → dicarbonyl(triphenylphosphine)[(1,2,3,4,5,6-η)-benzaldehyde]chromium (122114-08-3)

Guidance literature:

In not given; hydrolysis under N2; elem. anal.;;

DOI:10.1016/S0277-5387(00)80388-5

upstream raw materials:

[(1,2,3,4,5,6-η)benzaldehyde]tricarbonylchromium

triphenylphosphine

dioxolanebenzaldehyde chromium dicarbonyl triphenylphosphine