closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10]Cl

Base Information

Chemical Name:closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10]Cl
CAS No.:912336-72-2
Molecular Formula:C₁₆H₂₆B₉RuS*Cl
Molecular Weight:484.27
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10]Cl

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Technology Process of closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10]Cl

There total 1 articles about closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

: 37366-09-9
dichloro(benzene)ruthenium(II) dimer

: sodium hexaflorophosphate

: nido-[10-((C₆H₅)(C₂H₅)S)-7,8-C₂B₉H₁₁]

: [Ru(η5-10-HS-7,8-C2B9H10)(η6-C6H6)]

: 912336-72-2
closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10]Cl

: 912336-74-4
closo-[3-Ru(η6-benzene)-8-(C2H5)(C6H5)S-1,2-C2B9H10][PF6]

Guidance literature:: With t-BuOK; In tetrahydrofuran; ethanol; water; byproducts: KCl, C6H5Cl, C2H5Cl; under N2, Schlenk technique; B compd. treated with t-BuOK (0.489:1.0 molar ratio), stirred at room temp. for 30 min, Ru compd. (0.245 mmol) added, stirred for 2 d, septd., aq. soln. of NaPF6 (1.052 mmol) added; stirred at room temp. for 1 h, concd., crystd. on cooling, residue septd., washed (water), extd. (CH2Cl2), dried, supernatant THF soln. chromd. (SiO2, THF, CH2Cl2),NMR;
DOI:10.1002/ejic.200500470