cis-[(Ph₂PCH₂CH₂PPh₂)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃

Base Information

• Chemical Name: cis-[(Ph₂PCH₂CH₂PPh₂)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃
• CAS No.: 1214274-72-2
• Molecular Formula: C₃₈H₃₅N₄OP₂Pt*NO₃
• Molecular Weight: 882.755

Synonyms:

Chemical Property of cis-[(Ph₂PCH₂CH₂PPh₂)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃

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Technology Process of cis-[(Ph₂PCH₂CH₂PPh₂)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃

There total 1 articles about cis-[(Ph₂PCH₂CH₂PPh₂)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1-MeCyt (1122-47-0) + cis-[(Ph2PCH2CH2PPh2)2Pt(μ-OH)]2(NO3)2 + benzonitrile (100-47-0) → cis-[(Ph2PCH2CH2PPh2)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide(1-))]NO3 (1214274-72-2)

Guidance literature:

In benzonitrile; mixt. of Pt complex and 1-methylcytosine in PhCN stirred at room temp. for 1 d; filtered; Et2O added to filtrate; ppt. isolated; dried under vac.; elem.anal.;

DOI:10.1021/ic901508w

Reference yield:

cis-[(Ph2PCH2CH2PPh2)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide(1-))]NO3 (1214274-72-2) + acetylacetone (123-54-6,81235-32-7) → cis-[(Ph2PCH2CH2PPh2)Pt(acetylacetonate)]NO3

Guidance literature:

In acetylacetone; Pt complex dissolved in acetylacetone; not isolated; detd. by (31)P NMR spectra; equil. mixt. of initial and resultant Pt complexes obtained;

DOI:10.1021/ic901508w

Reference yield:

1,1,1,5,5,5-hexafluoroacetylacetone (1522-22-1) + cis-[(Ph2PCH2CH2PPh2)Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide(1-))]NO3 (1214274-72-2) → cis-[(Ph2PCH2CH2PPh2)Pt(hexafluoroacetylacetonate)]NO3

Guidance literature:

In further solvent(s); Pt complex dissolved in hexafluoroacetylacetone; not isolated; detd. by (31)P NMR spectra; equil. mixt. of initial and resultant Pt complexes (1:1.5) obtained;

DOI:10.1021/ic901508w

upstream raw materials:

1-MeCyt

benzonitrile

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