[(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)]

Base Information

Chemical Name:[(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)]
CAS No.:1260067-41-1
Molecular Formula:C₁₅H₁₄AuNS
Molecular Weight:437.315
Hs Code.:

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Chemical Property of [(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)]

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Technology Process of [(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)]

There total 2 articles about [(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 1192-39-8
(phenylthiolate)gold(I)

: 1260067-41-1
[(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)]

Guidance literature:: In tetrahydrofuran; soln. of isocyanide in THF was added to suspn. of Au compd. in THF; stirred for 25 min; concd. (vac.); dild. with light petroleum; kept in refrigerator for 3 h;light petroleum added; kept in refrigerator for 16 h; light petroleum a dded; after several h filtered; washed (light petroleum); dried in air; elem. anal.;
DOI:10.1007/s11172-010-0143-y

Reference yield: 38.0%

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 108-98-5
thiophenol

: 1260067-41-1
[(2,6-dimethylphenyl isocyanide)Au(benzenethiolate)]

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; soln. of BuLi in hexane was added to soln. of thiol in THF at -40°C in Schlenk app.; stirred for 30 min; Au complex was added at -30°C; soln. of isocyanide in THF was added; stirred for 30 min without forced cooling; filtered; concd. (vac.); dissolved in C6H6; light petroleum added;
DOI:10.1007/s11172-010-0143-y