[(Ru(CO)2Cl₂(P(CH₃)2C₆H₅))2]

Base Information

• Chemical Name: [(Ru(CO)2Cl₂(P(CH₃)2C₆H₅))2]
• CAS No.: 76565-44-1
• Molecular Formula: C₂₀H₂₂Cl₄O₄P₂Ru₂
• Molecular Weight: 732.292
• Mol file: 76565-44-1.mol

Synonyms:

Chemical Property of [(Ru(CO)2Cl₂(P(CH₃)2C₆H₅))2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Ru(CO)2Cl₂(P(CH₃)2C₆H₅))2]

There total 1 articles about [(Ru(CO)2Cl₂(P(CH₃)2C₆H₅))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

ruthenium(III) chloride trihydrate (14898-67-0) + Dimethyl(phenyl)phosphine (672-66-2) → [(Ru(CO)2Cl2(P(CH3)2C6H5))2] (76565-44-1)

Guidance literature:

With carbon monoxide; In 2-methoxy-ethanol; CO passed through a soln. of RuCl3*3H2O, refluxed for 5 h, addn. of PMe2Ph, reflux 19 h, the soln. cooled; ppt. washed with propanone;

DOI:10.1039/DT9800002418

Reference yield: 60.0%

Sn(C4H9)3(CHCH(CH3)CH2) + [(Ru(CO)2Cl2(P(CH3)2C6H5))2] (76565-44-1) → [Ru(CO)2Cl(η-1-MeC3H5)(PMePh2)] (76565-43-0,76821-80-2)

Guidance literature:

In acetone; stirred for 0.5 h under N2 atm.; evapd. of soln. in vac., addn. of water, ppt. filtered off, dried in vac., recrystn. from light petroleum; elem. anal.;

DOI:10.1039/DT9800002418

Reference yield: 60.0%

[(Ru(CO)2Cl2(P(CH3)2C6H5))2] (76565-44-1) + allyltributylstanane (24850-33-7) → [Ru(CO)2Cl(η-C3H5)(PMe2Ph)] (76747-84-7)

Guidance literature:

In acetone; stirred at 313 K for 0.5 h; removal of the solvent, chromy. on alumina, eluent CHCl3, crystd. from light petroleum; elem. anal.;

DOI:10.1039/DT9800002418

upstream raw materials:

ruthenium(III) chloride trihydrate

Dimethyl(phenyl)phosphine

Downstream raw materials:

[Ru(CO)2Cl(η-1-MeC3H5)(PMePh2)]

[Ru(CO)2Cl(η-C3H5)(PMe2Ph)]