phenylamidotris(carbon monoxide)bis(trimethylphosphine) rhenium(I)

Base Information

• Chemical Name: phenylamidotris(carbon monoxide)bis(trimethylphosphine) rhenium(I)
• CAS No.: 79485-49-7
• Molecular Formula: C₁₅H₂₄NO₃P₂Re
• Molecular Weight: 514.515
• Mol file: 79485-49-7.mol

Synonyms:

Chemical Property of phenylamidotris(carbon monoxide)bis(trimethylphosphine) rhenium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenylamidotris(carbon monoxide)bis(trimethylphosphine) rhenium(I)

There total 2 articles about phenylamidotris(carbon monoxide)bis(trimethylphosphine) rhenium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

phenylimidotrichlorobis(trimethylphosphine)rhenium(V) (172140-80-6,81986-17-6,82731-02-0) → phenylamidotris(carbon monoxide)bis(trimethylphosphine) rhenium(I) (79485-49-7,82009-97-0)

Guidance literature:

With Hg#Na; CO; In tetrahydrofuran; to a soln. of Re(NPh)Cl3(PMe3)2 in THF was added sodium amalgam in thf in a pressure bottle; after pressuring with CO the soln. was stirred at ambient temp. for 18 h; the bottle was repressurised periodically; filtered, evapd. to dryness under reduced pressure; extd. with light petroleum, filtered, concd. and cooled to -20°C; washed with light petroleum and dried; elem anal.;

DOI:10.1016/S0277-5387(00)81065-7

Reference yield:

{Re(NC6H5)Cl3(P(CH3)3)2} + carbon monoxide (201230-82-2) → Re(NHC6H5)(CO)3[P(CH3)3]2 (79485-49-7)

Guidance literature:

DOI:10.1039/c39810000451

upstream raw materials:

phenylimidotrichlorobis(trimethylphosphine)rhenium(V)

carbon monoxide