Fe(η5-2,5-dibenzoyl-3,4-dimethylphospholide)(η5-pentamethylcyclopentadienide)

Base Information

• Chemical Name: Fe(η5-2,5-dibenzoyl-3,4-dimethylphospholide)(η5-pentamethylcyclopentadienide)
• CAS No.: 1207847-87-7
• Molecular Formula: C₃₀H₃₁FeO₂P
• Molecular Weight: 510.396
• Mol file: 1207847-87-7.mol

Synonyms:

Chemical Property of Fe(η5-2,5-dibenzoyl-3,4-dimethylphospholide)(η5-pentamethylcyclopentadienide)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Fe(η5-2,5-dibenzoyl-3,4-dimethylphospholide)(η5-pentamethylcyclopentadienide)

There total 1 articles about Fe(η5-2,5-dibenzoyl-3,4-dimethylphospholide)(η5-pentamethylcyclopentadienide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

1,2,3,4,5-pentamethylcyclopentadiene (4045-44-7) + benzoyl chloride (98-88-4) + 3,4-dimethyl-1-phenylphosphole (30540-36-4) + iron(II) chloride → Fe(η5-2,5-dibenzoyl-3,4-dimethylphospholide)(η5-pentamethylcyclopentadienide) (1207847-87-7)

Guidance literature:

With (CH₃)3COK; CH₃CH₂CH₂CH₂Li; ZnCl₂; In tetrahydrofuran; prepn. of Me2(PhCO)2C4PK from PhPC4H2Me2, ClCOPh and tBuOK, treatment ofC5Me5H with BuLi in THF, addn. of phospholide deriv. and ZnCl2 in THF a t -78°C, addn. to FeCl2 in THF at -78°C, stirring for 30 min and at room temp. for 18 h; concg., dissolving in CH2Cl2, filtration through silica, concg., cold chromy. (silica, CH2Cl2/hexanes (1:1)), evapn., NMR and MS;

DOI:10.1021/om9010164

upstream raw materials:

1,2,3,4,5-pentamethylcyclopentadiene

benzoyl chloride

3,4-dimethyl-1-phenylphosphole