[N,N'-dimethyl-N,N'-di(3,4-diphenyl-η(5)-cyclopentadien)ethylenediamine]zirconium dichloride

Base Information

• Chemical Name: [N,N'-dimethyl-N,N'-di(3,4-diphenyl-η(5)-cyclopentadien)ethylenediamine]zirconium dichloride
• CAS No.: 179991-76-5
• Molecular Formula: C₃₈H₃₄Cl₂N₂Zr
• Molecular Weight: 680.831
• Mol file: 179991-76-5.mol

Synonyms:

Chemical Property of [N,N'-dimethyl-N,N'-di(3,4-diphenyl-η(5)-cyclopentadien)ethylenediamine]zirconium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N,N'-dimethyl-N,N'-di(3,4-diphenyl-η(5)-cyclopentadien)ethylenediamine]zirconium dichloride

There total 1 articles about [N,N'-dimethyl-N,N'-di(3,4-diphenyl-η(5)-cyclopentadien)ethylenediamine]zirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

zirconium(IV) chloride (10026-11-6) + N,N'-dimethyl-N,N'-bis(3,4-diphenylcyclopenta-1,3-dienyl)ethylenediamine (165751-37-1) → [N,N'-dimethyl-N,N'-di(3,4-diphenyl-η(5)-cyclopentadien)ethylenediamine]zirconium dichloride (179991-76-5)

Guidance literature:

With BuLi; In toluene; N2-atmosphere; treatment of ligand with BuLi for 1 h, ZrCl4 addn., refluxing for 3 d; hot filtration, evapn., recrystn. (PhMe/PE); elem. anal.;

DOI:10.1016/S0022-328X(96)06254-7

upstream raw materials:

zirconium(IV) chloride

N,N'-dimethyl-N,N'-bis(3,4-diphenylcyclopenta-1,3-dienyl)ethylenediamine