[Pt2(dppp)2(μ-S)2]

Base Information

• Chemical Name: [Pt2(dppp)2(μ-S)2]
• CAS No.: 442518-74-3
• Molecular Formula: C₅₄H₅₂P₄Pt₂S₂
• Molecular Weight: 1279.19
• Mol file: 442518-74-3.mol

Synonyms:

Chemical Property of [Pt2(dppp)2(μ-S)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt2(dppp)2(μ-S)2]

There total 1 articles about [Pt2(dppp)2(μ-S)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

sodiumsulfide nonahydrate + [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) → [Pt2(dppp)2(μ-S)2] (442518-74-3)

Guidance literature:

In benzene; byproducts: NaCl; under N2 atm. (PtCl2(dppp)) was added to benzene soln. Na2S*9H2O and stirred at room temp. for 8 h; react. mixt. was filtered, solvent was removed under vac.; elem. anal.;

DOI:10.1021/ic0107173

Reference yield: 82.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + [Pt2(dppp)2(μ-S)2] (442518-74-3) → [Pt3Cl2(μ3-S)2(dppp)2] (833453-55-7)

Guidance literature:

In benzene; under N2, 1:1 mixt. stirred at room temp. for 6 h; ppt. filtered off, washed (Et2O);

DOI:10.1002/ejic.200400257

Reference yield: 81.0%

ammonium hexafluorophosphate + [Pt2(dppp)2(μ-S)2] (442518-74-3) + benzyl bromide (100-39-0) → [Pt2(μ-SCH2C6H5)2(dppp)2](PF6)2

Guidance literature:

In methanol; (N2); addn. of benzyl bromide to soln. of platinum compd. in methanol, stirring at room temp. overnight, addn. of NH4PF6; addn. of deionized water, isolation of precipitate, washing with deionized water and ether using suction filtration, elem. anal.;

DOI:10.1039/b707526j

upstream raw materials:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

Downstream raw materials:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

[Pt2(dppp)2(μ-S)2]*Me2CO

[Pt3Cl2(μ3-S)2(dppp)2]

[Pt2(dppp)2(μ-S)(μ-SCH2CH(OH)CH2F)]F